The capacity of optical communication channels can be increased by space division multiplexing in structured optical fibers. Radial core optical fibers allows for the propagation of twisted light--eigenmodes of orbital angular momentum, which have attracted considerable attention for high-dimensional quantum information. Here we study the generation of entangled photons that are tailor-made for coupling into ring core optical fibers. We show that the coupling of photon pairs produced by parametric down-conversion can be increased by close to a factor of three by pumping the non-linear crystal with a perfect vortex mode with orbital angular momentum $ell$, rather than a gaussian mode. Moreover, the two-photon orbital angular momentum spectrum has a nearly constant shape. This provides an interesting scenario for quantum state engineering, as pumping the crystal with a superposition of perfect vortex modes can be used in conjunction with the mode filtering properties of the ring core fiber to produce simple and interesting quantum states.
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