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The Weyl semimetal MoTe$_2$ offers a rare opportunity to study the interplay between Weyl physics and superconductivity. Recent studies have found that Se substitution can boost the superconductivity up to 1.5K, but suppress the Td structure phase that is essential for the emergence of Weyl state. A microscopic understanding of possible coexistence of enhanced superconductivity and the Td phase has not been established so far. Here, we use scanning tunneling microscopy (STM) to study a optimally doped new superconductor MoTe$_{1.85}$Se$_{0.15}$ with bulk Tc ~ 1.5K. By means of quasiparticle interference imaging, we identify the existence of low temperature Td phase with broken inversion symmetry where superconductivity globally coexists. Consistently, we find that the superconducting coherence length, extracted from both the upper critical field and the decay of density of states near a vortex, is much larger than the characteristic length scale of existing dopant derived chemical disorder. Our findings of robust superconductivity arising from a Weyl semimetal normal phase in MoTe$_{1.85}$Se$_{0.15}$, makes it a promising candidate for realizing topological superconductivity.
This work presents the emergence of superconductivity in Ir - doped Weyl semimetal T$_d$ - MoTe$_{2}$ with broken inversion symmetry. Chiral anomaly induced planar Hall effect and anisotropic magneto-resistance confirm the topological semimetallic nature of Mo$_{1-x}$Ir$_{x}$Te$_{2}$. Observation of weak anisotropic, moderately coupled type-II superconductivity in T$_d$ -Mo$_{1-x}$Ir$_{x}$Te$_{2}$ makes it a promising candidate for topological superconductor.
Monolayer WTe$_2$, a centrosymmetric transition metal dichacogenide, has recently been established as a quantum spin Hall insulator and found superconducting upon gating. Here we study the pairing symmetry and topological nature of superconducting WTe$_2$ with a microscopic model at mean-field level. Surprisingly, we find that the spin-triplet phases in our phase diagram all host Majorana modes localized on two opposite corners. Even when the conventional pairing is favored, we find that an intermediate in-plane magnetic field exceeding the Pauli limit stabilizes an unconventional equal-spin pairing aligning with the field, which also hosts Majorana corner modes. Motivated by our findings, we obtain a recipe for two-dimensional superconductors featuring higher-order topology from the boundary perspective: Generally a superconducting inversion-symmetric quantum spin Hall material whose normal-state Fermi surface is away from high-symmetry points, such as gated monolayer WTe$_2$, hosts Majorana corner modes if the superconductivity is parity-odd. We further point out that this higher-order phase is an inversion-protected topological crystalline superconductor and study the bulk-boundary correspondence. Finally, we discuss possible experiments for probing the Majorana corner modes. Our findings suggest superconducting monolayer WTe$_2$ is a playground for higher-order topological superconductivity, and possibly the first material realization for inversion-protected Majorana corner modes without utilizing proximity effect.
Two-dimensional (2D) transition-metal dichalcogenide (TMDs) MoTe2 has attracted much attention due to its predicted Weyl semimetal (WSM) state and a quantum spin Hall insulator in bulk and monolayer form, respectively. We find that the superconductivity in MoTe2 single crystal can be much enhanced by the partial substitution of the Te ions by the S ones. The maximum of the superconducting temperature TC of MoTe1.8S0.2 single crystal is about 1.3 K. Compared with the parent MoTe2 single crystal (TC=0.1 K), nearly 13-fold in TC is improved in MoTe1.8S0.2 one. The superconductivity has been investigated by the resistivity and magnetization measurements. MoTe2-xSx single crystals belong to weak coupling superconductors and the improvement of the superconductivity may be related to the enhanced electron-phonon coupling induced by the S-ion substitution. A dome-shape superconducting phase diagram is obtained in the S-doped MoTe2 single crystals. MoTe2-xSx materials may provide a new platform for our understanding of superconductivity phenomena and topological physics in TMDs.
We perform single- and multi-band Migdal-Eliashberg (ME) calculations with parameters exctracted from density functional theory (DFT) simulations to study superconductivity in the electric-field-induced 2-dimensional hole gas at the hydrogenated (111) diamond surface. We show that according to the Eliashberg theory it is possible to induce a high-T$_{text{c}}$ superconducting phase when the system is field-effect doped to a surface hole concentration of $6times10^{14},$cm$^{-2}$, where the Fermi level crosses three valence bands. Starting from the band-resolved electron-phonon spectral functions $alpha^2F_{jj}(omega)$ computed ab initio, we iteratively solve the self-consistent isotropic Migdal-Eliashberg equations, in both the single-band and the multi-band formulations, in the approximation of a constant density of states at the Fermi level. In the single-band formulation, we find T$_{text{c}}approx40,$K, which is enhanced between $4%$ and $8%$ when the multi-band nature of the system is taken into account. We also compute the multi-band-sensistive quasiparticle density of states to act as a guideline for future experimental works.
Superconductivity (SC) in the Ba-122 family of iron-based compounds can be controlled by aliovalent or isovalent substitutions, applied external pressure, and strain, the combined effects of which are sometimes studied within the same sample. Most often, the result is limited to a shift of the SC dome to different doping values. In a few cases, the maximum SC transition at optimal doping can also be enhanced. In this work, we study the combination of charge doping together with isovalent P substitution and strain by performing ionic gating experiments on BaFe$_2$(As$_{0.8}$P$_{0.2}$)$_2$ ultrathin films. We show that the polarization of the ionic gate induces modulations to the normal-state transport properties that can be mainly ascribed to surface charge doping. We demonstrate that ionic gating can only shift the system away from the optimal conditions, as the SC transition temperature is suppressed by both electron and hole doping. We also observe a broadening of the resistive transition, which suggests that the SC order parameter is modulated nonhomogeneously across the film thickness, in contrast with earlier reports on charge-doped standard BCS superconductors and cuprates.