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Register a new userThe Reflectance Spectra of CV-CK Carbonaceous chondrites from the Near Infrared to the Visible
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Carbonaceous chondrite meteorites are so far the only available samples representing carbon-rich asteroids and in order to allow future comparison with samples returned by missions such as Hayabusa 2 and OSIRIS-Rex, is important to understand their physical properties. Future characterization of asteroid primitive classes, some of them targeted by sample-return missions, requires a better understanding of their mineralogy, the consequences of the exposure to space weathering, and how both affect the reflectance behavior of these objects. In this paper, the reflectance spectra of two chemically-related carbonaceous chondrites groups, precisely the Vigrano (CVs) and Karoonda (CKs), are measured and compared. The available sample suite includes polished sections exhibiting different petrologic types: from 3 (very low degree of thermal metamorphism) to 5 (high degree of thermal metamorphism). We found that the reflective properties and the comparison with the Cg asteroid reflectance class point toward a common chondritic reservoir from which the CV-CK asteroids collisionally evolved. In that scenario the CV and CK chondrites could be originated from 221 Eos asteroid family, but because of its collisional disruption, both chondrite groups evolved separately, experiencing different stages of thermal metamorphism, annealing and space weathering.
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We measured 3-micron reflectance spectra of 21 meteorites that represent all carbonaceous chondrite types available in terrestrial meteorite collections. The measurements were conducted at the Laboratory for Spectroscopy under Planetary Environmental Conditions (LabSPEC) at the Johns Hopkins University Applied Physics Laboratory (JHU APL) under vacuum and thermally-desiccated conditions (asteroid-like conditions). This is the most comprehensive 3-micron dataset of carbonaceous chondrites ever acquired in environments similar to the ones experienced by asteroids. The 3-micron reflectance spectra are extremely important for direct comparisons with and appropriate interpretations of reflectance data from ground-based telescopic and spacecraft observations of asteroids. We found good agreement between 3-{mu}m spectral characteristics of carbonaceous chondrites and carbonaceous chondrite classifications. The 3-{mu}m band is diverse, indicative of varying composition, thus suggesting that these carbonaceous chondrites experienced distinct parent body aqueous alteration and metamorphism environments.
We analyze here a wide sample of carbonaceous chondrites from historic falls (e.g. Allende, Cold Bokkeveld, Kainsaz, Leoville, Murchison, Murray and Orgueil), and from NASA Antarctic collection in order to get clues on the role of aqueous alteration in promoting the reflectance spectra diversity evidenced in the most primitive chondrite groups. We particularly focus in the identification of spectral features and behavior that can be used to remotely identify primitive carbonaceous asteroids. The selected meteorite specimens are a sample large enough to exemplify how laboratory reflectance spectra of rare groups of carbonaceous chondrites exhibit distinctive features that can be used to remotely characterize the spectra of primitive asteroids. Our spectra cover the full electromagnetic spectrum from 0.2 to 25 microns by using two spectrometers. First one is a UV-NIR spectrometer that covers the 0.2 to 2 microns window, while the second one is an Attenuated Total Reflectance IR spectrometer covering the 2 to 25 microns window. In particular, laboratory analyses in the UV-NIR window allow obtaining absolute reflectance by using standardized measurement procedures. We obtained reflectance spectra of specimens belonging to the CI, CM, CV, CR, CO, CK, CH, R, and CB groups of carbonaceous chondrites plus some ungrouped ones, and allows identifying characteristic features and bands for each class, plus getting clues on the influence of parent body aqueous alteration. These laboratory spectra can be compared with the remote spectra of asteroids, but the effects of terrestrial alteration forming (oxy)hydroxides need to be considered.
We study the visible and near-infrared (NIR) spectral properties of different ACO populations and compare them to the independently determined properties of comets. We select our ACOs sample based on published dynamical criteria and present our own observational results obtained using the 10.4m Gran Telescopio Canarias (GTC), the 4.2m William Herschel Telescope (WHT), the 3.56m Telescopio Nazionale Galileo (TNG), and the 2.5m Isaac Newton Telescope (INT), all located at the El Roque de los Muchachos Observatory (La Palma, Spain), and the 3.0m NASA Infrared Telescope Facility (IRTF), located at the Mauna Kea Observatory, in Hawaii. We include in the analysis the spectra of ACOs obtained from the literature. We derive the spectral class and the visible and NIR spectral slopes. We also study the presence of hydrated minerals by studying the 0.7 $mu$m band and the UV-drop below 0.5 $mu$m associated with phyllosilicates. We present new observations of 17 ACOs, 11 of them observed in the visible, 2 in the NIR and 4 in the visible and NIR. We also discuss the spectra of 12 ACOs obtained from the literature. All but two ACOs have a primitive-like class spectrum (X or D-type). Almost 100% of the ACOs in long-period cometary orbits (Damocloids) are D-types. Those in Jupiter family comet orbits (JFC-ACOs) are $sim$ 60% D-types and $sim$ 40% X-types. The mean spectral slope $S$ of JFC-ACOs is 9.7 $pm$ 4.6 %/1000 AA and for the Damocloids this is 12.2 $pm$ 2.0 %/1000 AA . No evidence of hydration on the surface of ACOs is found from their visible spectra. The slope and spectral class distribution of ACOs is similar to that of comets. The spectral classification, the spectral slope distribution of ACOs, and the lack of spectral features indicative of the presence of hydrated minerals on their surface, strongly suggest that ACOs are likely dormant or extinct comets.
The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X-ray absorption near-edge structure spectroscopy at the Fe-K- edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2 ((Fe2+) + 3(Fe3+))/FeTOT) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe3+ to Fe2+ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of 3+ 2+ 0 Fe is present, together with Fe and sometimes Fe. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least-altered CR chondrites, the fraction of Fe3+ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine-grained amorphous material in the matrix. Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together .
We report microscopic, cathodoluminescence, chemical and O isotopic measurements of FeO-poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2-ung), Northwest Africa 11086 (CM2-an), Allan Hills 77307 (CO3.0). The general petrographic, chemical and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand-alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO-rich refractory forsterites, which are restricted to $Delta^{17}O < -4permil$ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule-forming regions.
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