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Register a new userThe 3.3 $mu$m Infrared Emission Feature: Observational and Laboratory Constraints on Its Carrier
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Alan T. Tokunaga
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We examine the self-consistency of laboratory and observational data for potential carriers of the 3.3 $mu$m infrared emission feature (IEF), a member of the ubiquitous family of strong interstellar IEFs at 3.3, 3.4, 6.2, 7.7, 8.6, 11.2, and 12.7 $mu$m. Previous studies have shown that most Galactic sources (reflection nebulae, HII regions, and planetary nebulae) show 3.3 $mu$m IEFs displaying similar central wavelengths, full widths at half maximum, and profiles. Our study is focused on the band profile designated as Class A, the most prevalent of four classes of observed band profiles. In contrast to the observations, laboratory spectra for gas phase polycyclic aromatic hydrocarbons (PAHs), the widely assumed carriers of the IEFs, display central wavelength shifts, widths, and profiles that vary with temperature and PAH size. We present an extrapolation of the laboratory band shifts and widths for smaller PAHs ($le$32 carbon atoms) to the larger PAHs ($>$50 carbon atoms) that are thought to be the IEF carriers. The extrapolation leads to tight constraints on the sizes of the putative PAH carriers. Reconciling the observations with the implications of the laboratory spectra pose a significant challenge to the PAH and other IEF carrier hypotheses.
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We explore the relationships between the 3.3 {mu}m polycyclic aromatic hydrocarbon (PAH) feature and active galactic nucleus (AGN) properties of a sample of 54 hard X-ray selected bright AGNs, including both Seyfert 1 and Seyfert 2 type objects, using the InfraRed Camera (IRC) on board the infrared astronomical satellite AKARI. The sample is selected from the 9-month Swift/BAT survey in the 14-195 keV band and all of them have measured X-ray spectra at $E lesssim 10$ keV. These X-ray spectra provide measurements of the neutral hydrogen column density ($N_{rm H}$) towards the AGNs. We use the 3.3 {mu}m PAH luminosity ($L_{rm 3.3{mu}m}$) as a proxy for star formation activity and hard X-ray luminosity ($L_{rm 14-195keV}$) as an indicator of the AGN activity. We search for possible difference of star-formation activity between type 1 (un-absorbed) and type 2 (absorbed) AGNs. We have made several statistical analyses taking the upper-limits of the PAH lines into account utilizing survival analysis methods. The results of our $log(L_{rm 14-195keV})$ versus $log(L_{rm 3.3{mu}m})$ regression shows a positive correlation and the slope for the type 1/unobscured AGNs is steeper than that of type 2/obscured AGNs at a $3sigma$ level. Also our analysis show that the circum-nuclear star-formation is more enhanced in type 2/absorbed AGNs than type 1/un-absorbed AGNs for low X-ray luminosity/low Eddington ratio AGNs, while there is no significant dependence of star-formation activities on the AGN type in the high X-ray luminosities/Eddington ratios.
The 3.3 $mu$m unidentified infrared emission feature is commonly attributed to C-H stretching band of aromatic molecules. Astronomical observations have shown that this feature is composed of two separate bands at 3.28 and 3.30 $mu$m and the origin of these two bands is unclear. In this paper, we perform vibrational analyses based on quantum mechanical calculations of 153 organic molecules, including both pure aromatic molecules and molecules with mixed aromatic/olefinic/aliphatic hydridizations. We find that many of the C-H stretching vibrational modes in polycyclic aromatic hydrocarbon (PAH) molecules are coupled. Even considering the un-coupled modes only, the correlation between the band intensity ratios and the structure of the PAH molecule is not observed and the 3.28 and 3.30 $mu$m features cannot be directly interpreted in the PAH model. Based on these results, the possible aromatic, olefinic and aliphatic origins of the 3.3 $mu$m feature are discussed. We suggest that the 3.28 $mu$m feature is assigned to aromatic C-H stretch whereas the 3.30 $mu$m feature is olefinic. From the ratio of these two features, the relative olefinic to aromatic content of the carrier can be determined.
On 2019 August 14, the LIGO and Virgo interferometers detected a high-significance event labelled S190814bv. Preliminary analysis of the GW data suggests that the event was likely due to the merger of a compact binary system formed by a BH and a NS. ElectromagNetic counterparts of GRAvitational wave sources at the VEry Large Telescope (ENGRAVE) collaboration members carried out an intensive multi-epoch, multi-instrument observational campaign to identify the possible optical/near infrared counterpart of the event. In addition, the ATLAS, GOTO, GRAWITA-VST, Pan-STARRS and VINROUGE projects also carried out a search on this event. Our observations allow us to place limits on the presence of any counterpart and discuss the implications for the kilonova (KN) possibly generated by this NS-BH merger, and for the strategy of future searches. Altogether, our observations allow us to exclude a KN with large ejecta mass $Mgtrsim 0.1,mathrm{M_odot}$ to a high ($>90%$) confidence, and we can exclude much smaller masses in a subsample of our observations. This disfavours the tidal disruption of the neutron star during the merger. Despite the sensitive instruments involved in the campaign, given the distance of S190814bv we could not reach sufficiently deep limits to constrain a KN comparable in luminosity to AT 2017gfo on a large fraction of the localisation probability. This suggests that future (likely common) events at a few hundreds Mpc will be detected only by large facilities with both high sensitivity and large field of view. Galaxy-targeted observations can reach the needed depth over a relevant portion of the localisation probability with a smaller investment of resources, but the number of galaxies to be targeted in order to get a fairly complete coverage is large, even in the case of a localisation as good as that of this event.
Aims. The aim of this work is to further investigate the nature of PAH excitation and emission especially in the context of tracing star formation in a variety of extragalactic environments. Here we turn our attention to the energetic environment of the closest AGN in our sample, Centaurus A. Methods. Using ISAAC on the ESO VLT UT1 (Antu) we have made high spatial resolution 3.3 {mu}m imaging observations of the central kiloparsec of CenA. These observations have been compared with star formation tracers in the near- and mid-infrared, as well as with mid-infrared tracers of nuclear activity. Results. The nucleus is not devoid of PAH emission, implying that the PAH particles are not destroyed in the nucleus as might be expected for such a harsh environment. However, we see the feature to continuum ratio decrease towards the AGN. As well, the 3.3 {mu}m PAH feature emission generally traces the sites of star formation in Cen A, but in detail there are spatial offsets, consistent with an earlier study of the starburst galaxies NGC 253 and NGC 1808. However, the feature-to-continuum ratio does not drop at the positions of star formation as was previously seen in that earlier study. The cause for this difference remains uncertain. Finally, our data reveal possible evidence for a nearly face-on, circular or spiral, dust structure surrounding the nucleus.
The [CII] 157.74 $mu$m transition is the dominant coolant of the neutral interstellar gas, and has great potential as a star formation rate (SFR) tracer. Using the Herschel KINGFISH sample of 46 nearby galaxies, we investigate the relation of [CII] surface brightness and luminosity with SFR. We conclude that [CII] can be used for measurements of SFR on both global and kiloparsec scales in normal star-forming galaxies in the absence of strong active galactic nuclei (AGN). The uncertainty of the $Sigma_{rm [CII]}-Sigma_{rm SFR}$ calibration is $pm$0.21 dex. The main source of scatter in the correlation is associated with regions that exhibit warm IR colors, and we provide an adjustment based on IR color that reduces the scatter. We show that the color-adjusted $Sigma_{rm[CII]}-Sigma_{rm SFR}$ correlation is valid over almost 5 orders of magnitude in $Sigma_{rm SFR}$, holding for both normal star-forming galaxies and non-AGN luminous infrared galaxies. Using [CII] luminosity instead of surface brightness to estimate SFR suffers from worse systematics, frequently underpredicting SFR in luminous infrared galaxies even after IR color adjustment (although this depends on the SFR measure employed). We suspect that surface brightness relations are better behaved than the luminosity relations because the former are more closely related to the local far-UV field strength, most likely the main parameter controlling the efficiency of the conversion of far-UV radiation into gas heating. A simple model based on Starburst99 population-synthesis code to connect SFR to [CII] finds that heating efficiencies are $1%-3%$ in normal galaxies.
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