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Long-Range Superconducting Proximity Effect in Nickel Nanowires

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 Added by Cui-Zu Chang
 Publication date 2021
  fields Physics
and research's language is English




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When a ferromagnet is placed in contact with a superconductor, owing to incompatible spin order, the Cooper pairs from the superconductor cannot survive more than one or two nanometers inside the ferromagnet. This is confirmed in the measurements of ferromagnetic nickel (Ni) nanowires contacted by superconducting niobium (Nb) leads. However, when a thin copper (Cu) buffer layer (3 nm, oxidized due to exposure to air) is inserted between the Nb electrodes and the Ni wire, the spatial extent of the superconducting proximity range is dramatically increased from 2 to a few tens of nanometers. Scanning transmission electron microscope images verify the existence of Cu oxides and the magnetization measurements of such a 3 nm oxidized Cu film on a SiO2/Si substrate and on Nb/SiO2/Si show evidence of ferromagnetism. One way to understand the long-range proximity effect in the Ni nanowire is that the oxidized Cu buffer layer with ferromagnetism facilitates the conversion of singlet superconductivity in Nb into triplet supercurrent along the Ni nanowires.



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We report an experimental study of proximity effect-induced superconductivity in crystalline Cu and Co nanowires and a nanogranular Co nanowire structure in contact with a superconducting W floating electrode which we call inducer. The nanowires were grown by electrochemical deposition in heavy-ion-track etched polycarbonate templates. The nanogranular Co structure was fabricated by focused electron beam induced deposition (FEBID), while the amorphous W inducer was obtained by focused ion beam induced deposition (FIBID). For electrical resistance measurements up to three pairs of Pt voltage leads were deposited by FIBID at different distances beside the inner inducer electrode, thus allowing us to probe the proximity effect over a length of 2-12 $mu$m. Relative $R(T)$ drops of the same order of magnitude have been observed for the Co and Cu nanowires when sweeping the temperature below 5.2 K ($T_c$ of the FIBID-deposited W inducer). By contrast, relative $R(T)$ drops were found to be an order of magnitude smaller for the nanogranular Co nanowire structure. Our analysis of the resistance data shows that the superconducting proximity length in crystalline Cu and Co is about 1 $mu$m at low temperatures, attesting to a long-range proximity effect in the case of ferromagnetic Co. Moreover, this long-range proximity effect has been revealed to be insusceptible to magnetic fields up to 11 T, which is indicative of spin-triplet pairing. At the same time, in the nanogranular Co structure proximity-induced superconductivity is strongly suppressed due to the dominating Cooper pair scattering caused by the intrinsic microstructure of the FEBID deposit.
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