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Register a new userEffect of Al content on the hardness and thermal stability study of AlTiN and AlTiBN coatings deposited by HiPIMS
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Added by
Jon Molina-Aldareguia
Publication date
2021
fields
Physics
and research's language is
English
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The microstructure, mechanical properties and thermal stability of AlTiN and AlTiBN coatings grown by reactive high-power impulse magnetron sputtering (HiPIMS) have been analyzed as a function of Al/(Al+Ti) ratio, x, between 0.5 and 0.8. The coatings were predominantly formed by a face-centered cubic Ti(Al)N crystalline phase, both with and without B, even for x ratios as high as 0.6, which is higher than the ratio typically encountered for AlTiN coatings deposited by reactive magnetron sputtering. B doping, in combination with the highly energetic deposition conditions offered by HiPIMS, results in the suppression of the columnar grain morphology typically encountered in AlTiN coatings. On the contrary, the AlTiBN coatings grown by HiPIMS present a dense nanocomposite type microstructure, formed by nanocrystalline Ti(Al)N domains and amorphous regions composed of Ti(Al)B2 and BN. As a result, high-Al content (x>0.6) AlTiBN coatings grown by HiPIMS offer higher hardness, elasticity and fracture toughness than AlTiN coatings. Moreover, the thermal stability and the hot hardness are substantially enhanced, delaying the onset of formation of the detrimental hexagonal AlN phase from 850 C in the case of AlTiN, to 1000 C in the case of AlTiBN.
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Size dependent hardness has long been reported in nanosized indentations, however the corresponding explanation is still in exploration. In this paper, we examine the influence of surface energy on the hardness of materials under spherical indentation. To evaluate the ability of materials to resist indentation, a yield hardness is defined here as the contact pressure at the inception of material yield. It is found that this defined hardness is an intrinsic material property depending only on the yield strength and Poisson ratio in conventional continuum mechanics. Then, the impact of surface energy on the yield hardness is analyzed through finite element simulations. By using the dimensional analysis, the dependences of the yield hardness and critical indent depth at yield initiation on surface energy have been achieved. When the yield strength is comparable to the ratio of surface energy density to indenter radius, surface energy will alter the yield hardness and the critical indent depth. As the size of indenter decreases to nanoscale, both the yield hardness and the indent depth will increase significantly. This study provides a possible clarification to the size dependence of hardness and a potential approach to measure the yield strength and surface energy of solids through nanosized indentations.
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