Orbital eccentricity is one of the most robust discriminators for distinguishing between dynamical and isolated formation scenarios of binary black holes mergers using gravitational-wave observatories such as LIGO and Virgo. Using state-of-the-art cluster models, we show how selection effects impact the detectable distribution of eccentric mergers from clusters. We show that the observation (or lack thereof) of eccentric binary black hole mergers can significantly constrain the fraction of detectable systems that originate from dynamical environments such as dense star clusters. After roughly 150 observations, observing no eccentric binary signals would indicate that clusters cannot make up the majority of the merging binary black hole population in the local Universe (95% credibility). However, if dense star clusters dominate the rate of eccentric mergers and a single system is confirmed to be measurably eccentric in the first and second gravitational-wave transient catalogues, clusters must account for at least 14% of detectable binary black hole mergers. The constraints on the fraction of detectable systems from dense star clusters become significantly tighter as the number of eccentric observations grows, and will be constrained to within 0.5 dex once 10 eccentric binary black holes are observed.
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