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Inducing and optimizing Markovian Mpemba effect with stochastic reset

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 Publication date 2021
  fields Physics
and research's language is English




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A hot Markovian system can cool down faster than a colder one: this is known as the Mpemba effect. Here, we show that a non-equilibrium driving via stochastic reset can induce this phenomenon, when absent. Moreover, we derive an optimal driving protocol simultaneously optimizing the appearance time of the Mpemba effect, and the total energy dissipation into the environment, revealing the existence of a Pareto front. Building upon previous experimental results, our findings open up the avenue of possible experimental realizations of optimal cooling protocols in Markovian systems.



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Mpemba effect refers to the counterintuitive result that, when quenched to a low temperature, a system at higher temperature may equilibrate faster than one at intermediate temperatures. This effect has recently been demonstrated in driven granular gases, both for smooth as well as rough hard-sphere systems based on a perturbative analysis. In this paper, we consider the inelastic driven Maxwell gas, a simplified model for a granular gas, where the rate of collision is assumed to be independent of the relative velocity. Through an exact analysis, we determine the conditions under which a Mpemba effect is present in this model. For mono-dispersed gases, we show that the Mpemba effect is present only when the initial states are allowed to be non-stationary, while for bi-dispersed gases, it is present for steady state initial states. We also demonstrate the existence of the strong Mpemba effect for bi-dispersed Maxwell gas wherein the system at higher temperature relaxes to a final steady state at an exponentially faster rate leading to smaller equilibration time.
The Mpemba effect occurs when two samples at different initial temperatures evolve in such a way that the temperatures cross each other during the relaxation towards equilibrium. In this paper we show the emergence of a Mpemba-like effect in a molecular binary mixture in contact with a thermal reservoir (bath). The interaction between the gaseous particles of the mixture and the thermal reservoir is modeled via a viscous drag force plus a stochastic Langevin-like term. The presence of the external bath couples the time evolution of the total and partial temperatures of each component allowing the appearance of the Mpemba phenomenon, even when the initial temperature differences are of the same order of the temperatures themselves. Analytical results are obtained by considering multitemperature Maxwellian approximations for the velocity distribution functions of each component. The theoretical analysis is carried out for initial states close to and far away (large Mpemba-like effect) from equilibrium. The former situation allows us to develop a simple theory where the time evolution equation for the temperature is linearized around its asymptotic equilibrium solution. This linear theory provides an expression for the crossover time. We also provide a qualitative description of the large Mpemba effect. Our theoretical results agree very well with computer simulations obtained by numerically solving the Enskog kinetic equation by means of the direct simulation Monte Carlo method and by performing molecular dynamics simulations. Finally, preliminary results for driven granular mixtures also show the occurrence of a Mpemba-like effect for inelastic collisions.
Stochastic resets have lately emerged as a mechanism able to generate finite equilibrium mean square displacement (MSD) when they are applied to diffusive motion. Furthermore, walkers with an infinite mean first arrival time (MFAT) to a given position $x$, may reach it in a finite time when they reset their position. In this work we study these emerging phenomena from a unified perspective. On one hand we study the existence of a finite equilibrium MSD when resets are applied to random motion with $langle x^2(t)rangle _msim t^p$ for $0<pleq2$. For exponentially distributed reset times, a compact formula is derived for the equilibrium MSD of the overall process in terms of the mean reset time and the motion MSD. On the other hand, we also test the robustness of the finiteness of the MFAT for different motion dynamics which are subject to stochastic resets. Finally, we study a biased Brownian oscillator with resets with the general formulas derived in this work, finding its equilibrium first moment and MSD, and its MFAT to the minimum of the harmonic potential.
We demonstrate the existence, as well as determine the conditions, of a Mpemba effect - a counterintuitive phenomenon where a hotter system equilibrates faster than a cooler system when quenched to a cold temperature - in anisotropically driven granular gases. In contrast to earlier studies of Mpemba effect in granular systems, the initial states are stationary, making it a suitable system to experimentally study the effect. Our theoretical predictions for the regular, inverse and strong Mpemba effects agree well with results of event-driven molecular dynamics simulations of hard discs.
Through an exact analysis, we show the existence of Mpemba effect in an anisotropically driven inelastic Maxwell gas, a simplified model for granular gases, in two dimensions. Mpemba effect refers to the couterintuitive phenomenon of a hotter system relaxing to the steady state faster than a cooler system, when both are quenched to the same lower temperature. The Mpemba effect has been illustrated in earlier studies on isotropically driven granular gases, but its existence requires non-stationary initial states, limiting experimental realisation. In this paper, we demonstrate the existence of the Mpemba effect in anisotropically driven granular gases even when the initial states are non-equilibrium steady states. The precise conditions for the Mpemba effect, its inverse, and the stronger version, where the hotter system cools exponentially faster are derived.
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