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Register a new userOxygen out-diffusion in REBCO coated conductor due to heating
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Rare earth barium copper oxide (REBCO) coated conductor has emerged as one of the high Tc superconductors suitable for future ultrahigh field superconducting magnet applications. In the design and fabrication of such ultrahigh field REBCO magnets, it is essential to understand the behavior of REBCO coated conductor. The effect of heating on the properties of commercial REBCO coated conductors is very important for many practical reasons. Nevertheless, a comprehensive study on this effect have not yet been presented in the published literature. This work studies a commercial REBCO coated conductor heat-treated at temperatures between 175 {deg}C and 300 {deg}C for various durations. Critical current and lap joint resistivity were measured at 77 K and 4.2 K for the heat-treated samples. We found that critical current degrades with heat treatment time and temperature. This degradation can be described by a one-dimensional oxygen out-diffusion model with a diffusion coefficient of D = 2.5 x 10-6 exp (-1.17 eV/kT) m2/s. The heat treatment also causes appreciable increase in joint resistivity. Comprehensive structural and chemical analyses were performed on Cu/Ag/RECBO interfaces by transmission electron microscopy (TEM). Our electron energy loss spectroscopy (EELS) study provided direct evidence of oxygen deficiency in the heat treated REBCO samples. In addition, it is found that the oxygen diffused out of the REBCO layer forms mostly Cu2O at both Ag/REBCO and Cu/Ag interfaces. Cu2O is also observed at grain boundaries of the Ag layer. The oxygen out-diffusion model proposed in this work is used to predict REBCO thermal degradation in several engineering scenarios.
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High temperature superconducting coated conductor (CC) could be practically applied in electric equipment due to its favorable mechanical properties and the critical current performance of YBCO superconducting layer. It is well known that CC could be easily delaminated because of its poor stress tolerance in thickness direction, i.e. along the c-axis of YBCO. Commonly, a stack including YBCO layer and silver stabilizer could be obtained after the delamination. It would be interesting to investigate the superconducting properties of the delaminated stack, since it could also be considered as a new type of CC with the silver stabilizer as the buffer layer, which is quite different from the oxide buffer layers in the traditional CC and might lead to new applications. In this study, a CC sample was delaminated by liquid nitrogen immersing. A Hall probe scanning system was employed to measure the critical current (IC) distribution of the original sample and the obtained stack. It was found that IC could be partially preserved after the delamination. Dense and crack-free morphologies of the delaminated surfaces were observed by scanning electron microscopy, and the potential application of the obtained stack in superconducting joint technology was discussed.
We aim to demonstrate an efficient method to calculate the AC losses in multi-pancake coils. This method extends Yuan front-track model into several pancake application and investigates the detail parameters in comparison with established H-formula implemented in COMSOL and minimization of energy method. We use the front-track idea to analyze stacked pancakes assuming the current fronts are straight lines and using the critical state model. The current distribution is solved by two means: minimization of the perpendicular magnetic field in the subcritical region, as Clem and Yuan proposed; minimization of total magnetic energy. We also investigate the impacts of applied current and different gaps between multi pancakes on loss calculation. Our model provides a fast calculation method of AC loss in stacked (Re)BCO pancakes and is useful to HTS applications in high field magnets, energy storage devices and electric machines.
Transition metal oxide memristors, or resistive random-access memory (RRAM) switches, are under intense development for storage-class memory because of their favorable operating power, endurance, speed, and density. Their commercial deployment critically depends on predictive compact models based on understanding nanoscale physico-chemical forces, which remains elusive and controversial owing to the difficulties in directly observing atomic motions during resistive switching, Here, using scanning transmission synchrotron x-ray spectromicroscopy to study in-situ switching of hafnium oxide memristors, we directly observed the formation of a localized oxygen-deficiency-derived conductive channel surrounded by a low-conductivity ring of excess oxygen. Subsequent thermal annealing homogenized the segregated oxygen, resetting the cells towards their as-grown resistance state. We show that the formation and dissolution of the conduction channel are successfully modeled by radial thermophoresis and Fick diffusion of oxygen atoms driven by Joule heating. This confirmation and quantification of two opposing nanoscale radial forces that affect bipolar memristor switching are important components for any future physics-based compact model for the electronic switching of these devices.
In this work we present a modeling tool designed to estimate the hysteretic losses in the coils of an electric generator with coils made of coated conductor tapes during transient operation. The model is based on a two-stage segregated model approach that allows simulating the electric generator and the current distribution in the superconducting coils using a one-way coupling from the generator to the HTS coils model. The model has two inputs: the rotational speed and the electric load signal. A homogeneous anisotropic bulk model for the coils allows computing the current distribution in the coils. From this distribution, the hysteretic losses are estimated. Beyond the interest on providing an estimate on the global energy dissipation in the machine, in this work we present a more detailed local analysis that allows addressing issues such as coil design, critical current ratting, electric load change rate limits, cryocooler design, identification of quench-prone regions and overall transient performance.
The dissipative currents due to normal excitations are included in the London description. The resulting time dependent London equations are solved for a moving vortex and a moving vortex lattice. It is shown that the field distribution of a moving vortex looses it cylindrical symmetry, it experiences contraction which is stronger in the direction of the motion, than in the direction normal to the velocity $bm v$. The London contribution of normal currents to dissipation is small relative to the Bardeen-Stephen core dissipation at small velocities, but approaches the latter at high velocities, where this contribution is no longer proportional to $v^2$. To minimize the London contribution to dissipation, the vortex lattice orients as to have one of the unit cell vectors along the velocity, the effect seen in experiments and predicted within the time-dependent Ginzburg-Landau theory.
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