Relativistic quantum field theory in the presence of an external electric potential in a general curved space-time geometry is considered. The Fermi coordinates adapted to the time-like geodesic are utilized to describe the low-energy physics in the laboratory and to calculate the leading correction due to the curvature of the space-time geometry to the Schrodinger equation. The correction is employed to calculate the probability of excitation for a hydrogen atom that falls in or is scattered by a general Schwarzchild black hole. Since the excited states decay due to spontaneous photon emission, this study provides the theoretical base for detection of small isolated black holes by observing the decay of the excited states as neutral hydrogen atoms in the vacuum are devoured by the black hole.
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