Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userInfrared spectra of complex organic molecules in astronomically relevant ice matrices. III. Methyl formate and its tentative solid-state detection
104
0
0.0
(
0
)
Added by
Jeroen Terwisscha van Scheltinga
Publication date
2021
fields
Physics
and research's language is
English
Ask ChatGPT about the research
No Arabic abstract
Context. Infrared spectroscopy of star and planet forming regions is at the dawn of a new age with the upcoming James Webb Space Telescope. In support of these observations, laboratory spectra are required to identify complex organic molecules in the ices that cover the dust grains in these regions. Aims. This study aims to provide reference spectra to firmly detect icy methyl formate in the different stages of star and planet forming regions. Methyl formate is mixed in astronomically relevant matrices, and the peak positions, FWHMs, and relative band intensities are characterized for different temperatures to provide an analytical tool for astronomers. Methods. Methyl formate is deposited at 15 K under high-vacuum conditions. Specifically, methyl formate is deposited pure and mixed with CO, H$_2$CO, CH$_3$OH, H$_2$O, and CO:H$_2$CO:CH$_3$OH combined. Throughout the experiment infrared spectra are acquired with a FTIR spectrometer in the range from 4000-500 cm$^{-1}$ (2.5-20 $mu$m) at a spectral resolution of 0.5 cm$^{-1}$. Results. We present the characterization of five solid-state methyl formate vibrational modes in pure and astronomically relevant ice matrices. The five selected vibrational modes, namely the C=O stretch, C$-$O stretch, CH$_3$ rocking, O$-$CH$_3$ stretching, and OCO deformation, are best suited for a JWST identification of methyl formate. For each of these vibrational modes, and each of the mixtures the TvS heatmaps, peak position versus FWHM, and relative band intensities are given. Additionally, the acquired reference spectra of methyl formate are compared with Spitzer observations of HH 46. A tentative detection of methyl formate provides an upper limit to the column density of $1.7times10^{17}$ cm$^{-2}$, corresponding to an upper limit relative to water of $leq 2.2%$ and $leq 40%$ with respect to methanol.
rate research
Read More
High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The study of the deuteration of different molecules helps us to understand their formation. This is especially interesting for complex molecules such as methanol and bigger molecules for which it may allow to differentiate between gas-phase and solid-state formation pathways. Methanol exhibits a high deuterium fractionation in hot corinos. Since CH3OH is thought to be a precursor of methyl formate we expect that deuterated methyl formate is produced in such environments. We have searched for the singly-deuterated isotopologue of methyl formate, DCOOCH3, in IRAS 16293-2422, a hot corino well-known for its high degree of methanol deuteration. We have used the IRAM/JCMT unbiased spectral survey of IRAS 16293-2422 which allows us to search for the DCOOCH3 rotational transitions within the survey spectral range (80-280 GHz, 328-366 GHz). The expected emission of deuterated methyl formate is modelled at LTE and compared with the observations.} We have tentatively detected DCOOCH3 in the protostar IRAS 16293-2422. We assign eight lines detected in the IRAM survey to DCOOCH3. Three of these lines are affected by blending problems and one line is affected by calibration uncertainties, nevertheless the LTE emission model is compatible with the observations. A simple LTE modelling of the two cores in IRAS 16293-2422, based on a previous interferometric study of HCOOCH3, allows us to estimate the amount of DCOOCH3 in IRAS 16293-2422. Adopting an excitation temperature of 100 K and a source size of 2arcsec and 1farcs5 for the A and B cores, respectively, we find that N(A,DCOOCH3) = N(B,DCOOCH3) ~ 6.10^14 /cm2. The derived deuterium fractionation is ~ 15%, consistent with values for other deuterated species in this source and much greater than that expected from the deuterium cosmic abundance. DCOOCH3, if its tentative detection is confirmed, should now be considered in theoretical models that study complex molecule formation and their deuteration mechanisms. Experimental work is also needed to investigate the different chemical routes leading to the formation of deuterated methyl formate.
Since the start of ALMA observatory operation, new and important chemistry of infrared cold core was revealed. Molecular transitions at millimeter range are being used to identify and to characterize these sources. We have investigated the 231 GHz ALMA archive observations of the infrared dark cloud region C9, focusing on the brighter source that we called as IRDC-C9 Main. We report the existence of two sub-structures on the continuum map of this source: a compact bright spot with high chemistry diversity that we labelled as core, and a weaker and extended one, that we labelled as tail. In the core, we have identified lines of the molecules OCS(19-18), $^{13}$CS(5-4) and CH$_{3}$CH$_{2}$CN, several lines of CH$_{3}$CHO and the k-ladder emission of $^{13}$CH$_{3}$CN.We report two different temperature regions: while the rotation diagram of CH$_{3}$CHO indicates a temperature of 25 K, the rotation diagram of $^{13}$CH$_{3}$CN indicates a warmer phase at temperature of $sim450$K. In the tail, only the OCS(19-18) and $^{13}$CS(5-4) lines were detected. We used the $Nautilus$ and the textsc{Radex} codes to estimate the column densities and the abundances. The existence of hot gas in the core of IRDC-C9 Main suggests the presence of a protostar, which is not present in the tail.
The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) times 10^13 cm-2 and a rotational temperature of 7.6 pm 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium.
Millimeter and centimeter observations are discovering an increasing number of interstellar complex organic molecules (iCOMs) in a large variety of star forming sites, from the earliest stages of star formation to protoplanetary disks and in comets. In this context it is pivotal to understand how the solid phase interactions between iCOMs and grain surfaces influence the thermal desorption process and, therefore, the presence of molecular species in the gas phase. In laboratory, it is possible to simulate the thermal desorption process deriving important parameters such as the desorption temperatures and energies. We report new laboratory results on temperature-programmed desorption (TPD) from olivine dust of astrophysical relevant ice mixtures of water, acetonitrile, and acetaldehyde. We found that in the presence of grains, only a fraction of acetaldehyde and acetonitrile desorbs at about 100 K and 120 K respectively, while 40% of the molecules are retained by fluffy grains of the order of 100 {mu}m up to temperatures of 190-210 K. In contrast with the typical assumption that all molecules are desorbed in regions with temperatures higher than 100 K, this result implies that about 40% of the molecules can survive on the grains enabling the delivery of volatiles towards regions with temperatures as high as 200 K and shifting inwards the position of the snowlines in protoplanetary disks. These studies offer a necessary support to interpret observational data and may help our understanding of iCOMs formation providing an estimate of the fraction of molecules released at various temperatures.
Complex organic molecules (COMs), which are the seeds of prebiotic material and precursors of amino acids and sugars, form in the icy mantles of circumstellar dust grains but cannot be detected remotely unless they are heated and released to the gas phase. Around solar-mass stars, water and COMs only sublimate in the inner few au of the disk, making them extremely difficult to spatially resolve and study. Sudden increases in the luminosity of the central star will quickly expand the sublimation front (so-called snow line) to larger radii, as seen previously in the FU Ori outburst of the young star V883 Ori. In this paper, we take advantage of the rapid increase in disk temperature of V883 Ori to detect and analyze five different COMs, methanol, acetone, acetonitrile, acetaldehyde, and methyl formate, in spatially-resolved submillimeter observations. The COMs abundances in V883 Ori is in reasonable agreement with cometary values. This result suggests that outbursting young stars can provide a special opportunity to study the ice composition of material directly related to planet formation.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
