Electron collision cross sections in tetrafluoropropene HFO1234ze


Abstract in English

In the recent years, the hydrofluoroolefine HFO1234ze(E) (C3H2F4) has been subject to a growing interest for refrigerant applications. This novel gas is also considered a promising alternative in gaseous particle detectors and gaseous voltage insulation devices, thanks to its low global warming potential. In this contribution, measurements of electron transport coefficients and reaction rates in C3H2F4 are analyzed by an iterative procedure. A complete set of scattering cross sections for electrons in C3H2F4 has been obtained and validated by a systematic comparison of electron swarm parameters with experimental measurements in pure C3H2F4 as well as in gas mixtures of C3H2F4/CO2. Since the electron attachment of C3H2F4 is strongly influenced by the gas density, accurate calculations of the critical electric field strength in such mixtures are also reported in this paper.

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