High-spatial-resolution secondary ion mass spectrometry offers a method for mapping lithium at nanoscale lateral resolution. Practical implementation of this technique offers significant potential for revealing the distribution of Li in many materials with exceptional lateral resolution and elemental sensitivity. Here, two state-of-the-art methods are demonstrated on an aluminium-lithium alloy to visualise nanoscale Li-rich phases by mapping the 7Li+ secondary ion. NanoSIMS 50L analysis with a radio frequency O- plasma ion source enabled visualisation of needle-shaped T1 (Al2CuLi) phases as small as 75 nm in width. A compact time-of-flight secondary ion mass spectrometry detector added to a focused ion beam scanning electron microscope facilitated mapping of the T1 phases down to 45 nm in width using a Ga+ ion beam. Correlation with high resolution electron microscopy confirms the identification of T1 precipitates, their sizes and distribution observed during SIMS mapping.
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