Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userQuantum dynamics of Mn$^{2+}$ in dimethylammonium magnesium formate
297
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Dimethylammonium magnesium formate, [(CH$_3$)$_2$NH$_2$][Mg(HCOO)$_3$] or DMAMgF, is a model to study high temperature hybrid perovskite-like dielectrics. This compound displays a phase transition from para to ferroelectric at about 260~K. Using multifrequency electron spin resonance in continuous wave and pulsed modes, we herein present the quantum dynamic of Mn$^{2+}$ ion probe in DMAMgF. In the high temperature paraelectric phase, we observe a large distribution of the zero field splitting that is attributed to high local disorder and further supported by DFT computations. In the low temperature ferroelectric phase, a single structure phase is detected and shown to contain two magnetic structures. The complex EPR signals were identifed by the means of Rabi oscillation method combined to crystal fields kernel density estimation.
rate research
Read More
Magnesium alanate Mg(AlH4)2 has recently raised interest as a potential material for hydrogen storage. We apply ab initio calculations to characterize structural, electronic and energetic properties of Mg(AlH4)2. Density functional theory calculations within the generalized gradient approximation (GGA) are used to optimize the geometry and obtain the electronic structure. The latter is also studied by quasi-particle calculations at the GW level. Mg(AlH4)2 is a large band gap insulator with a fundamental band gap of 6.5 eV. The hydrogen atoms are bonded in AlH4 complexes, whose states dominate both the valence and the conduction bands. On the basis of total energies, the formation enthalpy of Mg(AlH4)2 with respect to bulk magnesium, bulk aluminum and hydrogen gas is 0.17 eV/H2 (at T = 0). Including corrections due to the zero point vibrations of the hydrogen atoms this number decreases to 0.10 eV/H2. The enthalpy of the dehydrogenation reaction Mg(AlH4)2 -> MgH2 +2Al+3H2(g) is close to zero, which impairs the potential usefulness of magnesium alanate as a hydrogen storage material.
The evolution of the magnetization in (Cd,Mn)Te quantum wells after a short pulse of magnetic field was determined from the giant Zeeman shift of spectroscopic lines. The dynamics in absence of magnetic field was found to be up to three orders of magnitude faster than that at 1 T. Hyperfine interaction and strain are mainly responsible for the fast decay. The influence of a hole gas is clearly visible: at zero field anisotropic holes stabilize the system of Mn ions, while in a magnetic field of 1 T they are known to speed up the decay by opening an additional relaxation channel.
Using dc and ac magnetometry, the pressure dependence of the magnetization of the three-dimensional antiferromagnetic coordination polymer Mn(N(CN)$_{2}$)$_{2}$ was studied up to 12 kbar and down to 8K. The magnetic transition temperature, $T_c$, increases dramatically with applied pressure $(P)$, where a change from $T_c(P=text{ambient}) = 16.0$ K to $T_c(P=12.1$~kbar$) = 23.5$ K was observed. In addition, a marked difference in the magnetic behavior is observed above and below 7.1 kbar. Specifically, for $P<7.1$ kbar, the differences between the field-cooled and zero-field-cooled (fc-zfc) magnetizations, the coercive field, and the remanent magnetization decrease with increasing pressure. However, for $P>7.1$ kbar, the behavior is inverted. Additionally, for $P>8.6$ kbar, minor hysteresis loops are observed. All of these effects are evidence of the increase of the superexchange interaction and the appearance of an enhanced exchange anisotropy with applied pressure.
We theoretically investigate the interplay between local lattice distortions around $rm{Mn^{2+}}$ ion impurity and the ions magnetic polarization, mediated through spin-orbit coupling of hole. We show that the tetrahedral symmetry around $rm{Mn^{2+}}$ ion impurity is spontaneously broken even in the paramagnetic regime. Modest local lattice distortions around the impurity $rm{Mn^{2+}}$ ion, along with the growth strain, stabilize magnetization along $< 110 >$ directions, in the ferromagnetic regime. We explain the experimentally observed in-plane uniaxial magnetic anisotropy seen in this system using this symmetry-breaking mechanism.
We report structural and physical properties of the single crystalline ${mathrm{Ca}}{mathrm{Mn}}_{2}{mathrm{P}}_{2}$. The X-ray diffraction(XRD) results show that ${mathrm{Ca}}{mathrm{Mn}}_{2}{mathrm{P}}_{2}$ adopts the trigonal ${mathrm{Ca}}{mathrm{Al}}_{2}{mathrm{Si}}_{2}$-type structure. Temperature dependent electrical resistivity $rho(T)$ measurements indicate an insulating ground state for ${mathrm{Ca}}{mathrm{Mn}}_{2}{mathrm{P}}_{2}$ with activation energies of 40 meV and 0.64 meV for two distinct regions, respectively. Magnetization measurements show no apparent magnetic phase transition under 400 K. Different from other ${mathrm{A}}{mathrm{Mn}}_{2}{mathrm{Pn}}_{2}$ (A = Ca, Sr, and Ba, and Pn = P, As, and Sb) compounds with the same structure, heat capacity $C_{mathrm{p}}(T)$ and $rho(T)$ reveal that ${mathrm{Ca}}{mathrm{Mn}}_{2}{mathrm{P}}_{2}$ has a first-order transition at $T$ = 69.5 K and the transition temperature shifts to high temperature upon increasing pressure. The emergence of plenty of new Raman modes below the transition, clearly suggests a change in symmetry accompanying the transition. The combination of the structural, transport, thermal and magnetic measurements, points to an unusual origin of the transition.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
