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Quantum annealing simulation of out-of-equilibrium magnetization in a spin-chain compound

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 Added by Andrew King
 Publication date 2021
  fields Physics
and research's language is English




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Geometrically frustrated spin-chain compounds such as Ca3Co2O6 exhibit extremely slow relaxation under a changing magnetic field. Consequently, both low-temperature laboratory experiments and Monte Carlo simulations have shown peculiar out-of-equilibrium magnetization curves, which arise from trapping in metastable configurations. In this work we simulate this phenomenon in a superconducting quantum annealing processor, allowing us to probe the impact of quantum fluctuations on both equilibrium and dynamics of the system. Increasing the quantum fluctuations with a transverse field reduces the impact of metastable traps in out-of-equilibrium samples, and aids the development of three-sublattice ferrimagnetic (up-up-down) long-range order. At equilibrium we identify a finite-temperature shoulder in the 1/3-to-saturated phase transition, promoted by quantum fluctuations but with entropic origin. This work demonstrates the viability of dynamical as well as equilibrium studies of frustrated magnetism using large-scale programmable quantum systems, and is therefore an important step toward programmable simulation of dynamics in materials using quantum hardware.

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We study the real-time dynamics of a small bubble of false vacuum in a quantum spin chain near criticality, where the low-energy physics is described by a relativistic (1+1)-dimensional quantum field theory. Such a bubble can be thought of as a confined kink-antikink pair (a meson). We carefully construct bubbles so that particle production does not occur until the walls collide. To achieve this in the presence of strong correlations, we extend a Matrix Product State (MPS) ansatz for quasiparticle wavepackets [Van Damme et al., arXiv:1907.02474 (2019)] to the case of confined, topological quasiparticles. By choosing the wavepacket width and the bubble size appropriately, we avoid strong lattice effects and observe relativistic kink-antikink collisions. We use the MPS quasiparticle ansatz to detect scattering outcomes: In the Ising model, with transverse and longitudinal fields, we do not observe particle production despite nonintegrability (supporting recent observations of nonthermalizing mesonic states). With additional interactions, we see production of confined and unconfined particle pairs. Although we simulated these low-energy, few-particle events with moderate resources, we observe significant growth of entanglement with energy and with the number of collisions, suggesting that increasing either will ultimately exhaust our methods. Quantum devices, in contrast, are not limited by entanglement production, and promise to allow us to go far beyond classical methods. We anticipate that kink-antikink scattering in 1+1 dimensions will be an instructive benchmark problem for relatively near-term quantum devices.
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The magnetic behavior of the Ca3Co2O6 spin chain compound is characterized by a large Ising-like character of its ferromagnetic chains, set on triangular lattice, that are antiferromagnetically coupled. At low temperature, T < 7K, the 3D antiferromagnetic state evolves towards a spin frozen state. In this temperature range, magnetic field driven magnetization of single crystals (H//chains) exhibits stepped variations. The occurrence of these steps at regular intervals of the applied magnetic field, Hstep=1.2T, is reminiscent of the quantum tunneling of the magnetization (QTM) of molecular based magnets. Magnetization relaxation experiments also strongly support the occurrence of this quantum phenomenon. This first observation of QTM in a magnetic oxide belonging to the large family of the A3BBO6 compounds opens new opportunities to study a quantum effect in a very different class of materials from molecular magnets.
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