No Arabic abstract
This review focuses on the investigation and enhancement of the thermoelectric properties of semiconducting nanowires (NWs). NWs are nanostructures with typical diameters between few to hundreds of nm and length of few to several microns, exhibiting a high surface-to-volume ratio. Nowadays an extraordinary control over their growth has been achieved, enabling also the integration of different types of heterostructures, which can lead to the engineering of the functional properties of the NWs. In this review, we discuss all concepts which have been presented and achieved so far for the improvements of the thermoelectric performances of semiconducting NWs. Furthermore, we present a brief survey of the experimental methods which enable the investigation of the thermoelectric properties of these nanostructures.
We study optical properties of arrays of ultrathin nanowires by means of the Brillouin scattering of light on magnons. We employ the Stokes/anti-Stokes scattering asymmetry to probe the circular polarization of a local electric field induced inside nanowires by linearly polarized light waves. We observe the anomalous polarization conversion of the opposite sign than that in a bulk medium or thick nanowires with a great enhancement of the degree of circular polarization attributed to an unconventional refraction in the nanowire medium.
The thermal conductance of straight and corrugated monocrystalline silicon nanowires has been measured between 0.3 K and 5 K. The difference in the thermal transport between corrugated nanowires and straight ones demonstrates a strong reduction in the mean free path of the phonons. This averaged mean free path is remarkably smaller than the smaller diameter of the nanowire, evidencing a phonon thermal transport reduced below the Casimir limit. Monte Carlo simulations highlight that this effect can be attributed to significant multiple scattering of ballistic phonons occuring on the corrugated surfaces. This result suggests an original approach to transforming a monocrystalline material into a phonon glass.
We have measured the electronic heat capacity of thin film nanowires of copper and silver at temperatures 0.1 - 0.3 K; the films were deposited by standard electron-beam evaporation. The specific heat of the Ag films of sub-100 nm thickness agrees with the bulk value and the free-electron estimate, whereas that of similar Cu films exceeds the corresponding reference values by one order of magnitude. The origin of the anomalously high heat capacity of copper films remains unknown for the moment. Based on the low heat capacity and the possibility to devise a tunnel probe thermometer on it, the Ag films form a promising absorber material, e.g., for micro-wave photon calorimetry.
We discuss the non-zero frequency noise of heat current with the explicit example of energy carried by thermal photons in a circuit. Instead of the standard circuit modelling that gives a convenient way of predicting time-averaged heat current, we describe a setup composed of two resistors forming the heat baths by collections of bosonic oscillators. In terms of average heat transport this model leads to identical results with the conventional one, but besides this, it yields a convenient way of dealing with noise as well. The non-zero frequency heat current noise does not vanish in equilibrium even at zero temperature, the result that is known for, e.g., electron tunneling. We present a modulation method that can convert the difficult-to-measure high frequency quantum noise down to zero frequency.
In recent years, the study of heat to work conversion has been re-invigorated by nanotechnology. Steady-state devices do this conversion without any macroscopic moving parts, through steady-state flows of microscopic particles such as electrons, photons, phonons, etc. This review aims to introduce some of the theories used to describe these steady-state flows in a variety of mesoscopic or nanoscale systems. These theories are introduced in the context of idealized machines which convert heat into electrical power (heat-engines) or convert electrical power into a heat flow (refrigerators). In this sense, the machines could be categorized as thermoelectrics, although this should be understood to include photovoltaics when the heat source is the sun. As quantum mechanics is important for most such machines, they fall into the field of quantum thermodynamics. In many cases, the machines we consider have few degrees of freedom, however the reservoirs of heat and work that they interact with are assumed to be macroscopic. This review discusses different theories which can take into account different aspects of mesoscopic and nanoscale physics, such as coherent quantum transport, magnetic-field induced effects (including topological ones such as the quantum Hall effect), and single electron charging effects. It discusses the efficiency of thermoelectric conversion, and the thermoelectric figure of merit. More specifically, the theories presented are (i) linear response theory with or without magnetic fields, (ii) Landauer scattering theory in the linear response regime and far from equilibrium, (iii) Green-Kubo formula for strongly interacting systems within the linear response regime, (iv) rate equation analysis for small quantum machines with or without ..... (SEE THE PDF FOR THE REST OF THIS ABSTRACT)