We study the statistical mechanics of binary systems under gravitational interaction of the Modified Newtonian Dynamics (MOND) in three-dimensional space. Considering the binary systems, in the microcanonical and canonical ensembles, we show that in the microcanonical systems, unlike the Newtonian gravity, there is a sharp phase transition, with a high-temperature homogeneous phase and a low temperature clumped binary one. Defining an order parameter in the canonical systems, we find a smoother phase transition and identify the corresponding critical temperature in terms of physical parameters of the binary system.
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