Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules resulting from the union of aromatic rings and related species, which are likely responsible for strong infrared emission features (3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 microns). In this work, using a sample of Seyfert galaxies (DL<100 Mpc), we compare the circumnuclear (inner kpc) PAH emission of AGN and star-forming (SF) control samples, and we investigate the difference between the central and extended PAH properties. We employ newly developed PAH diagnostic model grids, derived from theoretical spectra, to compare the predicted and observed PAH ratios. We use Spitzer/InfraRed Spectrograph spectral data for a large sample of Seyfert galaxies and SF galaxies. In general we find that SF galaxies and powerful Seyfert galaxies are located in different regions of the PAH diagnostic diagram, which indicates that the size and charge of the PAH molecules but also the nature and hardness of the radiation field that excite them are different. Our work indicates that powerful AGN seem to favour larger PAH molecules (Nc>400) as well as neutral species. By subtracting the central from the total spectra we are able to compare the PAH emission in the central/extended region of a small sample of AGN. In contrast with the findings for central regions of AGN-dominated systems, we find that the extended emission of both Seyfert types has similar PAH molecular size distribution and ionized fraction of molecules than in central regions of SF galaxies (100< Nc< 300).
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