This study presents an innovative solution for powering electric vehicles, named Charging-as-a-Service (CaaS), that concerns the potential large-scale adoption of light-duty electric vehicles (LDEV) in the Mobility-as-a-Service (MaaS) industry. Analogous to the MaaS, the core idea of the CaaS is to dispatch service vehicles (SVs) that carry modular battery units (MBUs) to provide LDEVs for mobility service with on-demand battery delivery. The CaaS system is expected to tackle major bottlenecks of a large-scale LDEV adoption in the MaaS industry due to the lack of charging infrastructure and excess waiting and charging time. A hybrid agent-based simulation model (HABM) is developed to model the dynamics of the CaaS system with SV agents, and a trip-based stationary charging probability distribution is introduced to simulate the generation of charging demand for LDEVs. Two dispatching algorithms are further developed to support the optimal operation of the CaaS. The model is validated by assuming electrifying all 13,000 yellow taxis in New York City (NYC) that follow the same daily trip patterns. Multiple scenarios are analyzed under various SV fleet sizes and dispatching strategies. The results suggest that optimal deployment of 250 SVs may serve the LDEV fleet in NYC with an average waiting time of 5 minutes, save the travel distance at over 50 miles per minute, and gain considerable profits of up to $50 per minute. This study offers significant insights into the feasibility, service efficiency, and financial sustainability for deploying city-wide CaaS systems to power the electric MaaS industry.