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Excitation of Polycyclic Aromatic Hydrocarbon (PAH) Emission: Dependence on Size Distribution, Ionization, and Starlight Spectrum and Intensity

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 Added by Bruce T. Draine
 Publication date 2020
  fields Physics
and research's language is English




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Using physical models, we study the sensitivity of polycyclic aromatic hydrocarbon (PAH) emission spectra to the character of the illuminating starlight, to the PAH size distribution, and to the PAH charge distribution. Starlight models considered range from the emission from a 3 Myr-old starburst, rich in far-ultraviolet (FUV) radiation, to the FUV-poor spectrum of the very old population of the M31 bulge. A wide range of starlight intensities is considered. The effects of reddening in dusty clouds are investigated for different starlight spectra. For a fixed PAH abundance parameter $q_{rm PAH}$ (the fraction of the total dust mass in PAHs with $<10^3$ C atoms), the fraction of the IR power appearing in the PAH emission features can vary by a factor of two as the starlight spectrum varies from FUV-poor (M31 bulge) to FUV-rich (young starburst). We show how $q_{rm PAH}$ can be measured from the strength of the 7.7$mu$m emission. The fractional power in the 17$mu$m feature can be suppressed by high starlight intensities.

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83 - G. J. Bendo , N. Lu , A. Zijlstra 2020
We have examined polycyclic aromatic hydrocarbon (PAH) excitation in a sample of 25 nearby face-on spiral galaxies using the ratio of mid-infrared PAH emission to dust mass. Within 11 of the galaxies, we found that the PAH excitation was straightforwardly linked to ultraviolet or mid-infrared star formation tracers, which, along with other results studying the relation of PAH emission to star formation, indicates that the PAHs are most strongly excited in dusty shells around the star forming regions. Within another 5 galaxies, the PAH emission is enhanced around star forming regions only at specific galactocentric radii. In 6 more galaxies, PAH excitation is more strongly correlated with the evolved stellar populations as traced by 3.6 micron emission. The results for the remaining 3 galaxies were ambiguous. The radial gradients of the PAH/dust ratios were generally not linked to log(O/H) gradients except when the log(O/H) gradients were relatively steep. Galaxies in which PAHs were excited by evolved stars had relatively high far-ultraviolet to mid-infrared ratios, indicating that variations in the link between PAH excitation and different stellar populations is linked to changes in dust attenuation within galaxies. Alternately, differences in morphology could make it more likely that PAHs are excited by evolved stars, as 5 of the 6 galaxies where this occurs are late-type flocculent spiral galaxies. These heterogeneous results demonstrate the complexity of describing PAH excitation and have broad implications for using PAH emission as a star formation tracer as well as for modelling dust emission and radiative transfer.
98 - T.Takagi , Y.Ohyama , T.Goto 2010
Using an AKARI multi-wavelength mid-infrared (IR) survey, we identify luminous starburst galaxies at z> 0.5 based on the PAH luminosity, and investigate the nature of these PAH-selected starbursts. An extragalactic survey with AKARI towards the north ecliptic pole (NEP), the NEP-Deep survey, is unique in terms of a comprehensive wavelength coverage from 2 to 24um using all 9 photometric bands of the InfraRed Camera (IRC). This survey allows us to photometrically identify galaxies whose mid-IR emission is clearly dominated by PAHs. We propose a single colour selection method to identify such galaxies, using two mid-IR flux ratios at 11-to-7um and 15-to-9um (PAH-to-continuum flux ratio in the rest-frame), which are useful to identify starburst galaxies at z~0.5 and 1, respectively. We perform a fitting of the spectral energy distributions (SEDs) from optical to mid-IR wavelengths, using an evolutionary starburst model with a proper treatment of radiative transfer (SBURT), in order to investigate their nature. The SBURT model reproduces observed optical-to-mid-IR SEDs of more than a half of PAH-selected galaxies. Based on the 8um luminosity, we find ultra luminous infrared galaxies (ULIRGs) among PAH-selected galaxies. Their PAH luminosity is higher than local ULIRGs with a similar luminosity, and the PAH-to-total IR luminosity ratio is consistent with that of less luminous starburst galaxies. They are a unique galaxy population at high redshifts and we call these PAH-selected ULIRGs PAH-luminous galaxies. Although they are not as massive as submillimetre galaxies at z~2, they have the stellar mass of >3x10^{10} Msun and therefore moderately massive.
We examine polycyclic aromatic hydrocarbon (PAH), dust and atomic/molecular emission toward the Galactic bulge using Spitzer Space Telescope observations of four fields: C32, C35, OGLE and NGC 6522. These fields are approximately centered on (l, b) = (0.0{deg}, 1.0{deg}), (0.0{deg}, -1.0{deg}), (0.4{deg}, -2.1{deg}) and (1.0{deg}, -3.8{deg}), respectively. Far-infrared photometric observations complement the Spitzer/IRS spectroscopic data and are used to construct spectral energy distributions. We find that the dust and PAH emission are exceptionally similar between C32 and C35 overall, in part explained due to their locations---they reside on or near boundaries of a 7 Myr-old Galactic outflow event and are partly shock-heated. Within the C32 and C35 fields, we identify a region of elevated H{alpha} emission that is coincident with elevated fine-structure and [O IV] line emission and weak PAH feature strengths. We are likely tracing a transition zone of the outflow into the nascent environment. PAH abundances in these fields are slightly depressed relative to typical ISM values. In the OGLE and NGC 6522 fields, we observe weak features on a continuum dominated by zodiacal dust. SED fitting indicates that thermal dust grains in C32 and C35 have comparable temperatures to those of diffuse, high-latitude cirrus clouds. Little variability is detected in the PAH properties between C32 and C35, indicating that a stable population of PAHs dominates the overall spectral appearance. In fact, their PAH features are exceptionally similar to that of the M82 superwind, emphasizing that we are probing a local Galactic wind environment.
We present a sample of resolved galactic HII regions and photodissociation regions (PDRs) observed with the Spitzer infrared spectrograph (IRS) in spectral mapping mode between the wavelengths of 5--15 $mu$m. For each object we have spectral maps at a spatial resolution of $sim$4 in which we have measured all of the mid-infrared emission and absorption features. These include the PAH emission bands, primarily at 6.2, 7.7, 8.6, 11.2 and 12.7 $mu$m, as well as the spectral emission lines of neon and sulfur and the absorption band caused by silicate dust at around 9.8 $mu$m. In this work we describe the data in detail, including the data reduction and measurement strategies, and subsequently present the PAH emission band intensity correlations for each of the objects and the sample as a whole. We find that there are distinct differences between the sources in the sample, with two main groups, the first comprising the HII regions and the second the reflection nebulae (RNe). Three sources, the reflection nebula NGC~7023, the Horsehead nebula PDR (an interface between the HII region IC~434 and the Orion B molecular cloud) and M 17, resist this categorization, with the Horsehead PDR points mimicking the RNe and the NGC~7023 fluxes displaying unique bifurcated appearance in our correlation plots. These discrepancies seem to be due to the very low radiation field experienced by the Horsehead PDR and the very clean separation between the PDR environment and a diffuse environment in the NGC~7023 observations.
118 - E. R. Micelotta 2009
Context: PAHs appear to be an ubiquitous interstellar dust component but the effects of shocks waves upon them have never been fully investigated. Aims: To study the effects of energetic (~0.01-1 keV) ion (H, He and C) and electron collisions on PAHs in interstellar shock waves.Methods: We calculate the ion-PAH and electron-PAH nuclear and electronic interactions, above the threshold for carbon atom loss from a PAH, in 50-200 km/s shock waves in the warm intercloud medium. Results: Interstellar PAHs (Nc = 50) do not survive in shocks with velocities greater than 100 km/s and larger PAHs (Nc = 200) are destroyed for shocks with velocities greater/equal to 125 km/s. For shocks in the ~75 - 100 km/s range, where destruction is not complete, the PAH structure is likely to be severely denatured by the loss of an important fraction (20-40%) of the carbon atoms. We derive typical PAH lifetimes of the order of a few x10^8 yr for the Galaxy. These results are robust and independent of the uncertainties in some key parameters that have yet to be well-determined experimentally. Conclusions: The observation of PAH emission in shock regions implies that that emission either arises outside the shocked region or that those regions entrain denser clumps that, unless they are completely ablated and eroded in the shocked gas, allow dust and PAHs to survive in extreme environments.
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