The monitoring of Cs-137 in seawater using scintillation detector relies on the spectrum analysis method to extract the Cs-137 concentration. And when in poor statistic situation, the calculation result of the traditional net peak area (NPA) method has a large uncertainty. We present a machine learning based method to better analyze the gamma-ray spectrum with low Cs-137 concentration. We apply multilayer perceptron (MLP) to analyze the 662 keV full energy peak of Cs-137 in the seawater spectrum. And the MLP can be trained with a few measured background spectrums by combining the simulated Cs-137 signal with measured background spectrums. Thus, it can save the time of preparing and measuring the standard samples for generating the training dataset. To validate the MLP-based method, we use Geant4 and background gamma-ray spectrums measured by a seaborne monitoring device to generate an independent test dataset to test the result by our method and the traditional NPA method. We find that the MLP-based method achieves a root mean squared error of 0.159, 2.3 times lower than that of the traditional net peak area method, indicating the MLP-based method improves the precision of Cs-137 concentration calculation
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