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Register a new userThe missing pieces of the PuO 2 nanoparticle puzzle
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The nanoscience field often produces results more mystifying than any other discipline. It has been argued that changes in the plutonium dioxide (PuO2) particle size from bulk to nano can have a drastic effect on PuO2 properties. Here we report a full characterization of PuO2 nanoparticles (NPs) at the atomic level and probe their local and electronic structures by a variety of methods available at the synchrotron.
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New sets of young M dwarfs with complex, sharp-peaked, and strictly periodic photometric modulations have recently been discovered with Kepler/K2 and TESS data. All of these targets are part of young star-forming associations. Suggested explanations range from accretion of dust disks to co-rotating clouds of material to stellar spots getting periodically occulted by spin-orbit-misaligned dust disks. Here we provide a comprehensive overview of all aspects of these hypotheses, and add more observational constraints in an effort to understand these objects with photometry from TESS and the SPECULOOS Southern Observatory (SSO). We scrutinize the hypotheses from three different angles: (1) we investigate the occurrence rates of these scenarios through existing young star catalogs; (2) we study the longevity of these features using over one year of combined photometry from TESS and SSO; and (3) we probe the expected color dependency with multi-color photometry from SSO. In this process, we also revisit the stellar parameters accounting for activity effects, study stellar flares as activity indicators over year-long time scales, and develop toy models to imitate typical morphologies. We identify which parts of the hypotheses hold true or are challenged by these new observations. So far, none of the hypotheses stand out as a definite answer, and each come with limitations. While the mystery of these complex rotators remains, we here add valuable observational pieces to the puzzle for all studies going forward.
We present the first analysis of the stellar content of the structures and substructures identified in the peculiar star-forming galaxy NGC5474, based on Hubble Space Telescope resolved photometry from the LEGUS survey. NGC5474 is a satellite of the giant spiral M101, and is known to have a prominent bulge that is significantly off-set from the kinematic center of the underlying HI and stellar disc. The youngest stars (age~ 100 Myr) trace a flocculent spiral pattern extending out to ~8 kpc from the center of the galaxy. On the other hand intermediate-age (age > 500 Myr) and old (age > 2 Gyr) stars dominate the off-centred bulge and a large substructure residing in the South Western part of the disc and not correlated with the spiral arms (SW over-density). The old age of the stars in the SW over-density suggests that this may be another signature of the dynamical interaction/s that have shaped this anomalous galaxy. We suggest that a fly by with M101, generally invoked as the origin of the anomalies, may not be sufficient to explain all the observations. A more local and more recent interaction may help to put all the pieces of this galactic puzzle together.
It has been known that when a charged fermion scatters off a monopole, the fermion in the $s$-wave component must flip its chirality, i.e., fermion number violation must happen. This fact has led to a puzzle; if there are two or more flavors of massless fermions, any superposition of the fermion states cannot be the final state of the $s$-wave scattering as it is forbidden by conservation of the electric and flavor charges. The unitary evolution of the state vector, on the other hand, requires some interpretation of the final states. We solve the puzzle by finding new particle excitations in the monopole background, where multi-fermion operators exhibit condensation. The particles are described as excitations of closed-string configurations of the condensates.
The outstanding discrepancy between the measured and calculated (local-density approximation) Fermi surfaces in the well-characterized, paramagnetic Fermi liquid Sr2RhO4 is resolved by including the spin-orbit coupling and Coulomb repulsion. This results in an effective spin-orbit coupling constant enhanced 2.15 times over the bare value. A simple formalism allows discussion of other systems. For Sr2RhO4, the experimental specific-heat and mass enhancements are found to be 2.2.
Electrostatic reaction inhibition in heterogeneous catalysis emerges if charged reactants and products are adsorbed on the catalyst and thus repel the approaching reactants. In this work, we study the effects of electrostatic inhibition on the reaction rate of unimolecular reactions catalyzed on the surface of a spherical model nanoparticle by using particle-based reaction-diffusion simulations. Moreover, we derive closed rate equations based on approximate Debye-Smoluchowski rate theory, valid for diffusion-controlled reactions, and a modified Langmuir adsorption isotherm, relevant for reaction-controlled reactions, to account for electrostatic inhibition in the Debye-Huckel limit. We study the kinetics of reactions ranging from low to high adsorptions on the nanoparticle surface and from the surface- to diffusion-controlled limits for charge valencies 1 and 2. In the diffusion-controlled limit, electrostatic inhibition drastically slows down the reactions for strong adsorption and low ionic concentration, which is well described by our theory. In particular, the rate decreases with adsorption affinity, because in this case the inhibiting products are generated at high rate. In the (slow) reaction-controlled limit, the effect of electrostatic inhibition is much weaker, as semi-quantitatively reproduced by our electrostatic-modified Langmuir theory. We finally propose and verify a simple interpolation formula that describes electrostatic inhibition for all reaction speeds (`diffusion-influenced reactions) in general.
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