Chaos is ubiquitous in physical systems. The associated sensitivity to initial conditions is a significant obstacle in forecasting the weather and other geophysical fluid flows. Data assimilation is the process whereby the uncertainty in initial conditions is reduced by the astute combination of model predictions and real-time data. This chapter reviews recent findings from investigations on the impact of chaos on data assimilation methods: for the Kalman filter and smoother in linear systems, analytic results are derived; for their ensemble-bas