We study and compare the time evolutions of concurrence and quantum discord in a driven system of two interacting qubits prepared in a generic Werner state. The~corresponding quantum dynamics is exactly treated and manifests the appearance and disappearance of entanglement. Our analytical treatment transparently unveils the physical reasons for the occurrence of such a phenomenon, relating it to the dynamical invariance of the $X$ structure of the initial state. The~quantum correlations which asymptotically emerge in the system are investigated in detail in terms of the time evolution of the fidelity of the initial Werner state.