The paper explores the correspondence between balanced incomplete block designs (BIBD) and certain linear CNF formulas by identifying the points of a block design with the clauses of the Boolean formula and blocks with Boolean variables. Parallel classes in BIBDs correspond to XSAT solutions in the corresponding formula. This correspondence allows for transfers of results from one field to the other. As a new result we deduce from known satisfiability theorems that the problem of finding a parallel class in a partially balanced incomplete block design is NP-complete.