The Hamiltonian system of general relativity and its quantization without any matter or gauge fields are discussed on the basis of the symplectic geometrical theory. A symplectic geometry of classical general relativity is constructed using a generalized phase space for pure gravity. Prequantization of the symplectic manifold is performed according to the standard procedure of geometrical quantization. Quantum vacuum solutions are chosen from among the classical solutions under the Einstein-Brillouin-Keller quantization condition. A topological correction of quantum solutions, namely the Maslov index, is realized using a prequantization bundle. In addition, a possible mass spectrum of Schwarzschild black holes is discussed.