No Arabic abstract
There is a growing family of rare-earth kagome materials with dominant nearest-neighbor interactions and strong spin orbit coupling. The low symmetry of these materials makes theoretical description complicated, with six distinct nearest-neighbor coupling parameters allowed. In this Article, we ask what kinds of classical, ordered, ground states can be expected to occur in these materials, assuming generic (i.e. non-fine-tuned) sets of exchange parameters. We use symmetry analysis to show that there are only five distinct classical ground state phases occurring for generic parameters. The five phases are: (i) a coplanar, 2-fold degenerate, state with vanishing magnetization (${sf A_1}$), (ii) a noncoplanar, 2-fold degenerate, state with magnetization perpendicular to the kagome plane (${sf A_2}$), (iii) a coplanar, 6-fold degenerate, state with magnetization lying within the kagome plane (${sf E}$-coplanar), (iv) a noncoplanar, 6-fold degenerate, state with magnetization lying within a mirror plane of the lattice (${sf E}$-noncoplanar$_{6}$), (v) a noncoplanar, 12-fold degenerate, state with magnetization in an arbitrary direction (${sf E}$-noncoplanar$_{12}$). All five are translation invariant (${bf q}=0$) states. Having found the set of possible ground states, the ground state phase diagram is obtained by comparing numerically optimized energies for each possibility as a function of the coupling parameters. The state ${sf E}$ noncoplanar$_{12}$ is extremely rare, occupying $<1%$ of the full phase diagram, so for practical purposes there are four main ordered states likely to occur in anisotropic kagome magnets with dominant nearest neighbor interactions. These results can aid in interpreting recent experiments on ``tripod kagome systems R$_3$A$_2$Sb$_3$O$_{14}$, as well as materials closer to the isotropic limit such as Cr- and Fe- jarosites.
The spin-$frac{1}{2}$ kagome antiferromagnet is considered an ideal host for a quantum spin liquid ground state. We find that when the bonds of the kagome lattice are modulated with a periodic pattern, new quantum ground states emerge. Newly synthesized crystalline barlowite (Cu$_4$(OH)$_6$FBr) and Zn-substituted barlowite demonstrate the delicate interplay between singlet states and spin order on the spin-$frac{1}{2}$ kagome lattice. Comprehensive structural measurements demonstrate that our new variant of barlowite maintains hexagonal symmetry at low temperatures with an arrangement of distorted and undistorted kagome triangles, for which numerical simulations predict a pinwheel valence bond crystal (VBC) state instead of a quantum spin liquid (QSL). The presence of interlayer spins eventually leads to an interesting pinwheel $q=0$ magnetic order. Partially Zn-substituted barlowite (Cu$_{3.44}$Zn$_{0.56}$(OH)$_6$FBr) has an ideal kagome lattice and shows QSL behavior, indicating a surprising robustness of the QSL against interlayer impurities. The magnetic susceptibility is similar to that of herbertsmithite, even though the Cu$^{2+}$ impurities are above the percolation threshold for the interlayer lattice and they couple more strongly to the nearest kagome moment. This system is a unique playground displaying QSL, VBC, and spin order, furthering our understanding of these highly competitive quantum states.
Motivated by recent experimental and theoretical progress on the Er2Ti2O7 pyrochlore XY antiferromagnet, we study the problem of quantum order-by-disorder in pyrochlore XY systems. We consider the most general nearest-neighbor pseudo spin-1/2 Hamiltonian for such a system characterized by anisotropic spin-spin couplings J_e = [J_pm, J_{pmpm}, J_{zpm}, J_{zz}] and construct zero-temperature phase diagrams. Combining symmetry arguments and spin-wave calculations, we show that the ground state phase boundaries between the two candidate ground states of the Gamma_5 irreducible representation, the psi_2 and psi_3 (basis) states, are rather accurately determined by a cubic equation in J_{pm}J_{pmpm})/J_{zpm}^2. Depending on the value of J_{zz}, there can be one or three phase boundaries that separate alternating regions of psi_2 and psi_3 states. In particular, we find for sufficiently small J_{zz}/J_{pm} a narrow psi_2 sliver sandwiched between two psi_3 regions in the J_{pmpm}/J_pm vs J_{zpm}/J_pm phase diagram. Our results further illustrate the very large potential sensitivity of the ground state of XY pyrochlore systems to minute changes in their spin Hamiltonian. Using the experimentally determined J_3 and g-tensor values for Er2Ti2O7, we show that the heretofore neglected long-range 1/r^3 magnetostatic dipole-dipole interactions do not change the conclusion that Er2Ti2O7 has a psi_2 ground state induced via a quantum order-by-disorder mechanism. We propose that the CdDy2Se4 chalcogenide spinel, in which the Dy^{3+} ions form a pyrochlore lattice and may be XY-like, could prove interesting to investigate.
The anisotropic-exchange spin-1/2 model on a triangular lattice has been used to describe the rare-earth chalcogenides, which may have exotic ground states. We investigate the quantum phase diagram of the model by using the projected entangled pair state (PEPS) method, and compare it to the classical phase diagram. Besides two stripe-ordered phase, and the 120$^circ$ state, there is also a multi-textbf{Q} phase. We identify the multi-textbf{Q} phase as a $Z_{2}$ vortex state. No quantum spin liquid state is found in the phase diagram, contrary to the previous DMRG calculations.
Exactly solvable models play a special role in Condensed Matter physics, serving as secure theoretical starting points for investigation of new phenomena. Changlani et al. [Phys. Rev. Lett. 120, 117202 (2018)] have discovered a limit of the XXZ model for $S=1/2$ spins on the kagome lattice, which is not only exactly solvable, but features a huge degeneracy of exact ground states corresponding to solutions of a three-coloring problem. This special point of the model was proposed as a parent for multiple phases in the wider phase diagram, including quantum spin liquids. Here, we show that the construction of Changlani et al. can be extended to more general forms of anisotropic exchange interaction, finding a line of parameter space in an XYZ model which maintains both the macroscopic degeneracy and the three-coloring structure of solutions. We show that the ground states along this line are partially ordered, in the sense that infinite-range correlations of some spin components coexist with a macroscopic number of undetermined degrees of freedom. We therefore propose the exactly solvable limit of the XYZ model on corner-sharing triangle-based lattices as a tractable starting point for discovery of quantum spin systems which mix ordered and spin liquid-like properties.
According to energy band theory, ground states of a normal conductor and insulator can be obtained by filling electrons individually into energy levels, without any restrictions. It fails when the electron-electron correlation is taken into account. In this work, we investigate dynamic process of building ground states of a Hubbard model. It bases on time-ordered quantum quenches for unidirectional hopping across a central and an auxiliary Hubbard models. We find that there exists a set of optimal parameters (chemical potentials and pair binding energy) for the auxiliary system, which takes the role of electron pair-reservoir. The exceptional dynamics allows the perfect transfer of electron pair from the reservoir to the central system, obtaining its ground states at different fillings. The dynamics of time-ordered pair-filling not only provides a method for correlated quantum state engineering, but also reveals the feature of the ground state in an alternative way.