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Register a new userInfluence of galactic arm scale dynamics on the molecular composition of the cold and dense ISM III. Elemental depletion and shortcomings of the current physico-chemical models
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We present a study of the elemental depletion in the interstellar medium. We combined the results of a Galatic model describing the gas physical conditions during the formation of dense cores with a full-gas-grain chemical model. During the transition between diffuse and dense medium, the reservoirs of elements, initially atomic in the gas, are gradually depleted on dust grains (with a phase of neutralisation for those which are ions). This process becomes efficient when the density is larger than 100~cm$^{-3}$. If the dense material goes back into diffuse conditions, these elements are brought back in the gas-phase because of photo-dissociations of the molecules on the ices followed by thermal desorption from the grains. Nothing remains on the grains for densities below 10~cm$^{-3}$ or in the gas-phase in a molecular form. One exception is chlorine, which is efficiently converted at low density. Our current gas-grain chemical model is not able to reproduce the depletion of atoms observed in the diffuse medium except for Cl which gas abundance follows the observed one in medium with densities smaller than 10~cm$^{-3}$. This is an indication that crucial processes (involving maybe chemisorption and/or ice irradiation profoundly modifying the nature of the ices) are missing.
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Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for astrochemical models. In this paper, we have combined the physical conditions computed with smoothed particle hydrodynamics (SPH) simulations with our full gas-grain chemical model Nautilus, to study the predicted O2 abundance in interstellar material forming cold cores. We thus follow the chemical evolution of gas and ices in parcels of material from the diffuse interstellar conditions to the cold dense cores. Most of our predicted O2 abundances are below 1e-8 (with respect to the total proton density) and the predicted column densities in simulated cold cores is at maximum a few 1e14 cm-2, in agreement with the non detection limits. This low O2 abundance can be explained by the fact that, in a large fraction of the interstellar material, the atomic oxygen is depleted onto the grain surface (and hydrogenated to form H2O) before O2 can be formed in the gas-phase and protected from UV photo-dissociations. We could achieve this result only because we took into account the full history of the evolution of the physical conditions from the diffuse medium to the cold cores.
Aims. We study the effect of large scale dynamics on the molecular composition of the dense interstellar medium during the transition between diffuse to dense clouds. Methods. We followed the formation of dense clouds (on sub-parsec scales) through the dynamics of the interstellar medium at galac- tic scales. We used results from smoothed particle hydrodynamics (SPH) simulations from which we extracted physical parameters that are used as inputs for our full gas-grain chemical model. In these simulations, the evolution of the interstellar matter is followed for ~50 Myr. The warm low-density interstellar medium gas flows into spiral arms where orbit crowding produces the shock formation of dense clouds, which are held together temporarily by the external pressure. Results. We show that depending on the physical history of each SPH particle, the molecular composition of the modeled dense clouds presents a high dispersion in the computed abundances even if the local physical properties are similar. We find that carbon chains are the most affected species and show that these differences are directly connected to differences in (1) the electronic fraction, (2) the C/O ratio, and (3) the local physical conditions. We argue that differences in the dynamical evolution of the gas that formed dense clouds could account for the molecular diversity observed between and within these clouds. Conclusions. This study shows the importance of past physical conditions in establishing the chemical composition of the dense medium.
It is important to understand the origin of molecular line intensities and chemical composition in the molecular-cloud scale in the Galactic sources because it serves as a benchmark to compare with the chemical compositions of extragalactic sources. Recent observations of the 3-mm spectra averaged over the 10-pc scale show similar spectral pattern among sources for molecular lines HCN, HCO$^+$, CCH, HNC, HNCO, c-C$_3$H$_2$, CS, SO, N$_2$H$^+$, and CN. To constrain the average physical property emitting such spectral pattern, we model molecular spectra using a time-dependent gas-grain chemical model followed by a radiative transfer calculation. We use a grid of physical parameters such as the density $n=3 times 10^2 - 3times 10^4$ cm$^{-3}$, the temperature, $T=10-30$ K, the visual extinction $A_{rm V} = 2,4,10$ mag, the cosmic-ray ionization rate $zeta = 10^{-17} - 10^{-16}$ s$^{-1}$, and the sulfur elemental abundance $S/H = 8times 10^{-8} - 8times 10^{-7}$. Comparison with the observed spectra indicates that spectra are well reproduced with the relatively low density of $n=(1-3) times 10^3,$cm$^{-3}$, $T=10,$K, $zeta = 10^{-17}$ s$^{-1}$, and the short chemistry timescale of $10^5$ yrs. This short chemistry timescale may indicate that molecular clouds are constantly affected by the turbulence, and exposed to low-density, low $A_{rm V}$ regions that refreshes the chemical clock by UV radiation. The relatively low density obtained is orders of magnitude lower than the commonly-quoted critical density in the optically thin case. Meanwhile, this range of density is consistent with results from recent observational analysis of molecular-cloud-scale mapping.
Type Ia supernovae are bright stellar explosions distinguished by standardizable light curves that allow for their use as distance indicators for cosmological studies. Despite the highly successful use of these events in this capacity, many fundamental questions remain. Contemporary research investigates how properties of the progenitor system that follow from the host galaxy such as composition and age influence the brightness of an event with the goal of better understanding and assessing the intrinsic scatter in the brightness. We provide an overview of these supernovae and proposed progenitor systems, all of which involve one or more compact stars known as white dwarfs. We describe contemporary research investigating how the composition and structure of the progenitor white dwarf systematically influences the explosion outcome assuming the progenitor is a single white dwarf that has gained mass from a companion. We present results illustrating some of these systematic effects from our research.
We examine the influence of the environment on the chemical abundances of late-type galaxies with masses of 10^9.1 M_sun - 10^11 M_sun using data from the Sloan Digital Sky Survey(SDSS). We find that the environmental influence on galactic chemical abundances is strongest for galaxies with masses of 10^9.1 M_sun to 10^9.6 Msun. The galaxies in the densest environments may exceed the average oxygen abundances by about 0.05 dex (the median value of the overabundances for 101 galaxies in the densest environments) and show higher abundances in nitrogen by about 0.1. The abundance excess decreases with increasing galaxy mass and with decreasing environmental density. Since only a small fraction of late-type galaxies is located in high-density environments these galaxies do not have a significant influence on the general X/H - M relation. The metallicity - mass relations for isolated galaxies and for galaxies with neighbors are very similar. The mean shift of non-isolated galaxies around the metallicity - mass relation traced by the isolated galaxies is less than 0.01 dex for oxygen and less than 0.02 dex for nitrogen. The scatter in the galactic chemical abundances is large for any number of neighbor galaxies (at any environmental density), i.e., galaxies with both enhanced and reduced abundances can be found at any environmental density. This suggests that environmental effects do not play a key role in evolution of late-type galaxies as was also concluded in some of the previous studies.
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