We have examined polycyclic aromatic hydrocarbon (PAH) excitation in a sample of 25 nearby face-on spiral galaxies using the ratio of mid-infrared PAH emission to dust mass. Within 11 of the galaxies, we found that the PAH excitation was straightforwardly linked to ultraviolet or mid-infrared star formation tracers, which, along with other results studying the relation of PAH emission to star formation, indicates that the PAHs are most strongly excited in dusty shells around the star forming regions. Within another 5 galaxies, the PAH emission is enhanced around star forming regions only at specific galactocentric radii. In 6 more galaxies, PAH excitation is more strongly correlated with the evolved stellar populations as traced by 3.6 micron emission. The results for the remaining 3 galaxies were ambiguous. The radial gradients of the PAH/dust ratios were generally not linked to log(O/H) gradients except when the log(O/H) gradients were relatively steep. Galaxies in which PAHs were excited by evolved stars had relatively high far-ultraviolet to mid-infrared ratios, indicating that variations in the link between PAH excitation and different stellar populations is linked to changes in dust attenuation within galaxies. Alternately, differences in morphology could make it more likely that PAHs are excited by evolved stars, as 5 of the 6 galaxies where this occurs are late-type flocculent spiral galaxies. These heterogeneous results demonstrate the complexity of describing PAH excitation and have broad implications for using PAH emission as a star formation tracer as well as for modelling dust emission and radiative transfer.
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