We present a multi-wavelength investigation of a large-scale physical system containing the W33 complex. The extended system (~50 pc x 37 pc) is selected based on the distribution of molecular gas at [29.6, 60.2] km/s and of 88 ATLASGAL 870 micron dust clumps at d ~2.6 kpc. The extended system/molecular cloud traced in the maps of 13CO and C18O emission contains several HII regions excited by OB stars (age ~0.3-1.0 Myr) and a thermally supercritical filament (fs1, length ~17 pc). The filament, devoid of the ionized gas, shows dust temperature (T_d) of ~19 K, while the HII regions are depicted with T_d of ~21-29 K. It suggests the existence of two distinct environments in the cloud. The distribution of Class I young stellar objects (mean age ~0.44 Myr) traces the early stage of star formation (SF) toward the cloud. At least three velocity components (around 35, 45, and 53 km/s) are investigated toward the system. The analysis of 13CO and C18O reveals the spatial and velocity connections of cloud components around 35 and 53 km/s. The observed positions of previously known sources, W33 Main, W33 A and O4-7I stars, are found toward a complementary distribution of these two cloud components. The filament fs1 and a previously known object W33 B are seen toward the overlapping areas of the clouds, where ongoing SF activity is evident. A scenario concerning the converging/colliding flows from two different velocity components appears to explain well the observed signposts of SF activities in the system.
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