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Register a new userEquilibrium properties of two-species reactive lattice gases on random catalytic chains
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We focus here on the thermodynamic properties of adsorbates formed by two-species $A+B to oslash$ reactions on a one-dimensional infinite lattice with heterogeneous catalytic properties. In our model hard-core $A$ and $B$ particles undergo continuous exchanges with their reservoirs and react when dissimilar species appear at neighboring lattice sites in presence of a catalyst. The latter is modeled by supposing either that randomly chosen bonds in the lattice promote reactions (Model I) or that reactions are activated by randomly chosen lattice sites (Model II). In the case of annealed disorder in spatial distribution of a catalyst we calculate the pressure of the adsorbate by solving three-site (Model I) or four-site (Model II) recursions obeyed by the corresponding averaged grand-canonical partition functions. In the case of quenched disorder, we use two complementary approaches to find $textit{exact}$ expressions for the pressure. The first approach is based on direct combinatorial arguments. In the second approach, we frame the model in terms of random matrices; the pressure is then represented as an averaged logarithm of the trace of a product of random $3 times 3$ matrices -- either uncorrelated (Model I) or sequentially correlated (Model II).
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We study equilibrium properties of catalytically-activated $A + A to oslash$ reactions taking place on a lattice of adsorption sites. The particles undergo continuous exchanges with a reservoir maintained at a constant chemical potential $mu$ and react when they appear at the neighbouring sites, provided that some reactive conditions are fulfilled. We model the latter in two different ways: In the Model I some fraction $p$ of the {em bonds} connecting neighbouring sites possesses special catalytic properties such that any two $A$s appearing on the sites connected by such a bond instantaneously react and desorb. In the Model II some fraction $p$ of the adsorption {em sites} possesses such properties and neighbouring particles react if at least one of them resides on a catalytic site. For the case of textit{annealed} disorder in the distribution of the catalyst, which is tantamount to the situation when the reaction may take place at any point on the lattice but happens with a finite probability $p$, we provide an exact solution for both models for the interior of an infinitely large Cayley tree - the so-called Bethe lattice. We show that both models exhibit a rich critical behaviour: For the annealed Model I it is characterised by a transition into an ordered state and a re-entrant transition into a disordered phase, which both are continuous. For the annealed Model II, which represents a rather exotic model of statistical mechanics in which interactions of any particle with its environment have a peculiar Boolean form, the transition to an ordered state is always continuous, while the re-entrant transition into the disordered phase may be either continuous or discontinuous, depending on the value of $p$.
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We employ Monte Carlo simulations to study the non-equilibrium relaxation of driven Ising lattice gases in two dimensions. Whereas the temporal scaling of the density auto-correlation function in the non-equilibrium steady state does not allow a precise measurement of the critical exponents, these can be accurately determined from the aging scaling of the two-time auto-correlations and the order parameter evolution following a quench to the critical point. We obtain excellent agreement with renormalization group predictions based on the standard Langevin representation of driven Ising lattice gases.
We discuss the scaling of the interaction energy with particle numbers for a harmonically trapped two-species mixture at thermal equilibrium experiencing interactions of arbitrary strength and range. In the limit of long-range interactions and weak coupling, we recover known results for the integrable Caldeira-Leggett model in the classical limit. In the case of short-range interactions and for a balanced mixture, numerical simulations show scaling laws with exponents that depend on the interaction strength, its attractive or repulsive nature, and the dimensionality of the system. Simple analytic considerations based on equilibrium statistical mechanics and small interspecies coupling quantitatively recover the numerical results. The dependence of the scaling on interaction strength helps to identify a threshold between two distinct regimes. Our thermalization model covers both local and extended interactions allowing for interpolation between different systems such as fully ionized gases and neutral atoms, as well as parameters describing integrable and chaotic dynamics.
We introduce a pair of time-reversible models defined on the discrete space-time lattice with 3 states per site, specifically, a vacancy and a particle of two flavours (species). The local update rules reproduce the rule 54 reversible cellular automaton when only a single species of particles is present, and satisfy the requirements of flavour exchange (C), space-reversal (P), and time-reversal (T) symmetries. We find closed-form expressions for three local conserved charges and provide an explicit matrix product form of the grand canonical Gibbs states, which are identical for both models. For one of the models this family of Gibbs states seems to be a complete characterisation of equilibrium (i.e. space and time translation invariant) states, while for the other model we empirically find a sequence of local conserved charges, one for each support size larger than 2, hinting to its algebraic integrability. Finally, we numerically investigate the behaviour of spatio-temporal correlation functions of charge densities, and test the prediction of nonlinear fluctuating hydrodynamics for the model with exactly three local charges. The numerically observed sound velocity deviates from the hydrodynamic prediction. The deviations are either significant, or they decay extremely slowly with the simulation time, which leaves us with an open question for the mechanism of such a glassy behaviour in a deterministic locally interacting system.
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