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Here we report a comparison between reflectance spectroscopy of meteorites under asteroidal environment (high vacuum and temperature) and Main Belt and Near Earth Asteroids spectra. Focusing on the OH absorption feature around 3{mu}m, we show that the asteroidal environment induces a reduction of depth and width of the band, as well as a shift of the reflectance minimum. We then decompose the OH feature into several components with a new model using Exponentially Modified Gaussians. Unlike previous studies, we confirme the link between these components, the aqueous alteration history and the amount of water molecules inside of the sample, using the shape of this spectral feature only. We then apply this deconvolution model to asteroids spectra which were obtained with a space-borne telescope and two space probes, and find a strong similarity with the components detected on meteorites, and among asteroids from a same type. Based on the conclusions drawn from our meteorites experiment, we suggest to use the 3-{mu}m band as a tracer of the alteration history of the small bodies. Using the 3-{mu}m band only, we show that Ryugu has been heavily altered by water, which is consistent with its parent body being covered with water ice, then went through a high temperature sequence, over 400{deg}C. We also point out that the 3-{mu}m band of Bennu shows signs of its newly discovered surface activity.
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We present here a new method to model the shape of the 3-{mu}m absorption band in the reflectance spectra of meteorites and small bodies. The band is decomposed into several OH/H2O components using Exponentially Modified Gaussian (EMG) profiles, as well as possible organic components using Gaussian profiles when present. We compare this model to polynomial and multiple Gaussian profile fits and show that the EMGs model returns the best rendering of the shape of the band, with significantly lower residuals. We also propose as an example an algorithm to estimate the error on the band parameters using a bootstrap method. We then present an application of the model to two spectral analyses of smectites subjected to different H2O vapor pressures, and present the variations of the components with decreasing humidity. This example emphasizes the ability of this model to coherently retrieve weak bands that are hidden within much stronger ones.
Most C-complex asteroids have albedo values less than 0.1, but there are some high-albedo (bright) C-complex asteroids with albedo values exceeding 0.1. To reveal the nature and origin of bright C-complex asteroids, we conducted spectroscopic observations of the asteroids in visible and near-infrared wavelength regions. As a result, the bright B-, C-, and Ch-type (Bus) asteroids, which are subclasses of the Bus C-complex, are classified as DeMeo C-type asteroids with concave curvature, B-, Xn-, and K-type asteroids. Analogue meteorites and material (CV/CK chondrites, enstatite chondrites/achondrites, and salts) associated with these spectral types of asteroids are thought to be composed of minerals and material exposed to high temperatures. A comparison of the results obtained in this study with the SDSS photometric data suggests that salts may have occurred in the parent bodies of 24 Themis and 10 Hygiea, as well as 2 Pallas. The bright C-complex asteroids in other C-complex families were likely caused by impact heating. Bright C-complex asteroids that do not belong to any families are likely to be impact metamorphosed carbonaceous chondrites, CV/CK chondrites, or enstatite chondrites/achondrites.
We report microscopic, cathodoluminescence, chemical and O isotopic measurements of FeO-poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2-ung), Northwest Africa 11086 (CM2-an), Allan Hills 77307 (CO3.0). The general petrographic, chemical and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand-alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO-rich refractory forsterites, which are restricted to $Delta^{17}O < -4permil$ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule-forming regions.
The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X-ray absorption near-edge structure spectroscopy at the Fe-K- edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2 ((Fe2+) + 3(Fe3+))/FeTOT) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe3+ to Fe2+ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of 3+ 2+ 0 Fe is present, together with Fe and sometimes Fe. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least-altered CR chondrites, the fraction of Fe3+ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine-grained amorphous material in the matrix. Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together .
The Sloan Digital Sky Survey provides colors for more than 100 000 moving objects, among which around 10 000 have albedos determined. Here we combined colors and albedo in order to perform a cluster analysis on the small bodies population, and identify a C-cluster, a group of asteroid related to C-type as defined in earlier work. Members of this C-cluster are in fair agreement with the color boundaries of B and C-type defined in DeMeo and Carry (2013). We then compare colors of C-cluster asteroids to those of carbonaceous chondrites powders, while taking into account the effect of phase angle. We show that only CM chondrites have colors in the range of C-cluster asteroids, CO, CR and CV chondrites being significantly redder. Also, CM chondrites powders are on average slightly redder than the average C-cluster. The colors of C-cluster members are further investigated by looking at color variations as a function of asteroid diameter. We observe that the visible slope becomes bluer with decreasing asteroids diameter, and a transition seems to be present around 20 km. We discuss the origin of this variation and, if not related to a bias in the dataset - analysis, we conclude that it is related to the surface texture of the objects, smaller objects being covered by rocks, while larger objects are covered by a particulate surface. The blueing is interpreted by an increased contribution of the first reflection in the case of rock-dominated surfaces, which can scatter light in a Rayleigh-like manner. We do not have unambiguous evidence of space weathering within the C-cluster based on this analysis, however the generally bluer nature of C-cluster objects compared to CM chondrites could be to some extent related to space weathering.
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