Let $G$ be a reductive algebraic group---possibly non-connected---over a field $k$ and let $H$ be a subgroup of $G$. If $G= GL_n$ then there is a degeneration process for obtaining from $H$ a completely reducible subgroup $H$ of $G$; one takes a limit of $H$ along a cocharacter of $G$ in an appropriate sense. We generalise this idea to arbitrary reductive $G$ using the notion of $G$-complete reducibility and results from geometric invariant theory over non-algebraically closed fields due to the authors and Herpel. Our construction produces a $G$-completely reducible subgroup $H$ of $G$, unique up to $G(k)$-conjugacy, which we call a $k$-semisimplification of $H$. This gives a single unifying construction which extends various special cases in the literature (in particular, it agrees with the usual notion for $G= GL_n$ and with Serres $G$-analogue of semisimplification for subgroups of $G(k)$). We also show that under some extra hypotheses, one can pick $H$ in a more canonical way using the Tits Centre Conjecture for spherical buildings and/or the theory of optimal destabilising cocharacters introduced by Hesselink, Kempf and Rousseau.
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