Most natural and artificial materials have crystalline structures from which abundant topological phases emerge [1-6]. The bulk-edge correspondence, widely-adopted in experiments to determine the band topology from edge properties, however, becomes inadequate in discerning various topological crystalline phases [7-17], leading to great challenges in the experimental classification of the large family of topological crystalline materials [4-6]. Theories predict that disclinations, ubiquitous crystallographic defects, provide an effective probe of crystalline topology beyond edges [18-21], which, however, has not yet been confirmed in experiments. Here, we report the experimental discovery of the bulk-disclination correspondence which is manifested as the fractional spectral charge and robust bound states at the disclinations. The fractional disclination charge originates from the symmetry-protected bulk charge patterns---a fundamental property of many topological crystalline insulators (TCIs). Meanwhile, the robust bound states at disclinations emerge as a secondary, but directly observable property of TCIs. Using reconfigurable photonic crystals as photonic TCIs with higher-order topology, we observe those hallmark features via pump-probe and near-field detection measurements. Both the fractional charge and the localized states are demonstrated to emerge at the disclination in the TCI phase but vanish in the trivial phase. The experimental discovery of bulk-disclination correspondence unveils a novel fundamental phenomenon and a new paradigm for exploring topological materials.
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