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Register a new userThe nonextensive statistical ensembles with dual thermodynamic interpretations
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The nonextensive statistical ensembles are revisited for the complex systems with long-range interactions and long-range correlations. An approximation, the value of nonextensive parameter (1-q) is assumed to be very tiny, is adopted for the limit of large particle number for most normal systems. In this case, Tsallis entropy can be expanded as a function of energy and particle number fluctuation, and thus the power-law forms of the generalized Gibbs distribution and grand canonical distribution can be derived. These new distribution functions can be applied to derive the free energy and grand thermodynamic potential in nonextensive thermodynamics. In order to establish appropriate nonextensive thermodynamic formalism, the dual thermodynamic interpretations are necessary for thermodynamic relations and thermodynamic quantities. By using a new technique of parameter transformation, the single-particle distribution can be deduced from the power-law Gibbs distribution. This technique produces a link between the statistical ensemble and the quasi-independent system with two kinds of nonextensive parameter having quite different physical explanations. Furthermore, the technique is used to construct nonextensive quantum statistics and effectively to avoid the factorization difficulty in the power-law grand canonical distribution.
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We study the thermodynamic properties of solid and metal electrons in the nonextensive quantum statistics with a nonextensive parameter transformation. First we study the nonextensive grand canonical distribution function and the nonextensive quantum statistics with a parameter transformation. Then we derive the generalized Boson distribution and Fermi distribution in the nonextensive quantum statistics. Further we study the thermodynamic properties of solid and metal electrons in the nonextensive quantum system, including the generalized Debye models, the generalized internal energies, the generalized capacities and chemical potential. We derive new expressions of these thermodynamic quantities, and we show that they all depend significantly on the nonextensive parameter and in the limit they recover to the forms in the classical quantum statistics. These new expressions may be applied to study the new characteristics in some nonextensive quantum systems where the long-range interactions and/or long-range correlations play a role.
We study the nonextensive thermodynamics for open systems. On the basis of the maximum entropy principle, the dual power-law q-distribution functions are re-deduced by using the dual particle number definitions and assuming that the chemical potential is constant in the two sets of parallel formalisms, where the fundamental thermodynamic equations with dual interpretations of thermodynamic quantities are derived for the open systems. By introducing parallel structures of Legendre transformations, other thermodynamic equations with dual interpretations of quantities are also deduced in the open systems, and then several dual thermodynamic relations are inferred. One can easily find that there are correlations between the dual relations, from which an equivalent rule is found that the Tsallis factor is invariable in calculations of partial derivative with constant volume or constant entropy. Using this rule, more correlations can be found. And the statistical expressions of the Lagrange internal energy and pressure are easily obtained.
We introduce a two-dimensional growth model where every new site is located, at a distance $r$ from the barycenter of the pre-existing graph, according to the probability law $1/r^{2+alpha_G} (alpha_G ge 0)$, and is attached to (only) one pre-existing site with a probability $propto k_i/r^{alpha_A}_i (alpha_A ge 0$; $k_i$ is the number of links of the $i^{th}$ site of the pre-existing graph, and $r_i$ its distance to the new site). Then we numerically determine that the probability distribution for a site to have $k$ links is asymptotically given, for all values of $alpha_G$, by $P(k) propto e_q^{-k/kappa}$, where $e_q^x equiv [1+(1-q)x]^{1/(1-q)}$ is the function naturally emerging within nonextensive statistical mechanics. The entropic index is numerically given (at least for $alpha_A$ not too large) by $q = 1+(1/3) e^{-0.526 alpha_A}$, and the characteristic number of links by $kappa simeq 0.1+0.08 alpha_A$. The $alpha_A=0$ particular case belongs to the same universality class to which the Barabasi-Albert model belongs. In addition to this, we have numerically studied the rate at which the average number of links $<k_i>$ increases with the scaled time $t/i$; asymptotically, $<k_i > propto (t/i)^beta$, the exponent being close to $beta={1/2}(1-alpha_A)$ for $0 le alpha_A le 1$, and zero otherwise. The present results reinforce the conjecture that the microscopic dynamics of nonextensive systems typically build (for instance, in Gibbs $Gamma$-space for Hamiltonian systems) a scale-free network.
We propose a two-parametric non-distributive algebraic structure that follows from $(q,q)$-logarithm and $(q,q)$-exponential functions. Properties of generalized $(q,q)$-operators are analyzed. We also generalize the proposal into a multi-parametric structure (generalization of logarithm and exponential functions and the corresponding algebraic operators). All $n$-parameter expressions recover $(n-1)$-generalization when the corresponding $q_nto1$. Nonextensive statistical mechanics has been the source of successive generalizations of entropic forms and mathematical structures, in which this work is a consequence.
After a brief review of the present status of nonextensive statistical mechanics, we present a conjectural scenario where mixing (characterized by the entropic index $q_{mix} le 1$) and equilibration (characterized by the entropic index $q_{eq} ge 1$) play central and inter-related roles, and appear to determine {it a priori} the values of the relevant indices of the formalism. Boltzmann-Gibbs statistical mechanics is recovered as the $q_{mix}=q_{eq}=1$ particular case.
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