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Register a new userSoft nanobubbles can deform rigid glasses
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Confined glasses and their anomalous interfacial rheology raise important questions in fundamental research and numerous practical applications. In this Letter, we study the influence of interfacial air nanobubbles on the free surface of ultrathin high-molecular-weight glassy polystyrene films immersed in water, in ambient conditions. In particular, we reveal the counterintuitive fact that a soft nanobubble is able to deform the surface of a rigid glass, forming a nanocrater with a depth that increases with time. By combining in-situ atomic-force-microscopy measurements and a modified lubrication model for the liquid-like layer at the free surface of the glass, we demonstrate that the capillary pressure in the nanobubble together with the liquid-like layer at the free surface of the glass determine the spatiotemporal growth of the nanocraters. Finally, from the excellent agreement between the experimental profiles and the numerical solutions of the governing glassy thin-film equation, we are able to precisely extract the surface mobility of the glass. In addition to revealing and quantifying how surface nanobubbles deform immersed glasses, until the latter eventually dewet from their substrates, our work provides a novel, precise, and simple measurement of the surface nanorheology of glasses.
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Inelastic deformation of metallic glasses occurs via slip events with avalanche dynamics similar to those of earthquakes. For the first time in these materials, measurements have been obtained with sufficiently high temporal resolution to extract both the exponents and the scaling functions that describe the nature, statistics and dynamics of the slips according to a simple mean-field model. These slips originate from localized deformation in shear bands. The mean-field model describes the slip process as an avalanche of rearrangements of atoms in shear transformation zones (STZs). Small slips show the predicted power-law scaling and correspond to limited propagation of a shear front, while large slips are associated with uniform shear on unconstrained shear bands. The agreement between the model and data across multiple independent measures of slip statistics and dynamics provides compelling evidence for slip avalanches of STZs as the elementary mechanism of inhomogeneous deformation in metallic glasses.
Topological mechanics can realize soft modes in mechanical metamaterials in which the number of degrees of freedom for particle motion is finely balanced by the constraints provided by interparticle interactions. However, solid objects are generally hyperstatic (or overconstrained). Here, we show how symmetries may be applied to generate topological soft modes even in overconstrained, rigid systems. To do so, we consider non-Hermitian topology based on non-square matrices, and design a hyperstatic material in which low-energy modes protected by topology and symmetry appear at interfaces. Our approach presents a novel way of generating softness in robust scale-free architectures suitable for miniaturization to the nanoscale.
The history dependence of the glasses formed from flow-melted steady states by a sudden cessation of the shear rate $dotgamma$ is studied in colloidal suspensions, by molecular dynamics simulations, and mode-coupling theory. In an ideal glass, stresses relax only partially, leaving behind a finite persistent residual stress. For intermediate times, relaxation curves scale as a function of $dotgamma t$, even though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this history dependence of glasses sharing the same thermodynamic state variables, but differing static properties.
The temperature dependence of the thermal conductivity is linked to the nature of the energy transport at a frequency omega, which is quantified by thermal diffusivity d(omega). Here we study d(omega) for a poorly annealed glass and a highly stable glass prepared using the swap Monte Carlo algorithm. To calculate d(omega), we excite wave packets and find that the energy moves diffusively for high frequencies up to a maximum frequency, beyond which the energy stays localized. At intermediate frequencies, we find a linear increase of the square of the width of the wave packet with time, which allows for a robust calculation of d(omega), but the wave packet is no longer well described by a Gaussian as for high frequencies. In this intermediate regime, there is a transition from a nearly frequency independent thermal diffusivity at high frequencies to d(omega) ~ omega^(-4) at low frequencies. For low frequencies the sound waves are responsible for energy transport and the energy moves ballistically. The low frequency behavior can be predicted using sound attenuation coefficients.
We image local structural rearrangements in soft colloidal glasses under small periodic perturbations induced by thermal cycling. Local structural entropy $S_{2}$ positively correlates with observed rearrangements in colloidal glasses. The high $S_{2}$ values of the rearranging clusters in glasses indicate that fragile regions in glasses are structurally less correlated, similar to structural defects in crystalline solids. Slow-evolving high $S_{2}$ spots are capable of predicting local rearrangements long before the relaxations occur, while fluctuation-created high $S_{2}$ spots best correlate with local deformations right before the rearrangement events. Local free volumes are also found to correlate with particle rearrangements at extreme values, although the ability to identify relaxation sites is substantially lower than $S_{2}$. Our experiments provide an efficient structural identifier for the fragile regions in glasses, and highlight the important role of structural correlations in the physics of glasses.
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