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Register a new userX-rays induced atomic dynamics in a lithium-borate glass
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The continuous development of synchrotron-based experimental techniques in the X-ray range provides new possibilities to probe the structure and the dynamics of bulk materials down to inter-atomic distances. However, the interaction of intense X-ray beams with matter can also induce changes in the structure and dynamics of materials. A reversible and non-destructive beam induced dynamics has recently been observed in X-ray photon correlation spectroscopy experiments in some oxide glasses at sufficiently low absorbed doses, and is here investigated in a (Li$_2$O)$_{0.5}$(B$_2$O$_3$)$_{0.5}$ glass. The characteristic time of this induced dynamics is inversely proportional to the intensity of the X-ray beam, with a coefficient that depends on the chemical composition and local structure of the probed glass, making it a potentially new tool to investigate fundamental properties of a large class of disordered systems. While the exact mechanisms behind this phenomenon are yet to be elucidated, we report here on the measurement of the exchanged wave-vector (and thus length-scale) dependence of the characteristic time of this induced dynamics, and show that it follows the same power-law observed in vitreous silica. This supports the idea that a unique explanation for this effect in different oxide glasses should be looked for.
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Applying coherent X-rays by the method of atomic-scale X-ray Photon Correlation Spectroscopy results in beam-induced dynamics in a number of oxide glasses. Here these studies are extended to rubidium and caesium borates with varying alkali contents. While no cumulative beam damage is observed, the observed rate of structural rearrangements shows a linear relation to the dose rate. In agreement with the increasing glass transition temperature, the rate of dynamics at given dose rate decreases with increasing alkali content, while the shape of the decay of correlations becomes progressively stretched. This behavior is explained in terms of faster dynamics of the alkali positions compared to the borate network. Finally, the q-dependent behavior of the correlation decay rate implies the observed dynamics to proceed via small-scale atomic displacements subject to de Gennes narrowing.
The high frequency dynamics of glassy Selenium has been studied by Inelastic X-ray Scattering at beamline BL35XU (SPring-8). The high quality of the data allows one to pinpoint the existence of a dispersing acoustic mode for wavevectors ($Q$) of $1.5<Q<12.5$ nm$^{-1}$, helping to clarify a previous contradiction between experimental and numerical results. The sound velocity shows a positive dispersion, exceeding the hydrodynamic value by $approx$ 10% at $Q<3.5$ nm$^{-1}$. The $Q^2$ dependence of the sound attenuation $Gamma(Q)$, reported for other glasses, is found to be the low-$Q$ limit of a more general $Gamma(Q) propto Omega(Q)^2$ law which applies also to the higher $Q$ region, where $Omega(Q)propto Q$ no longer holds.
Spin glasses and many-body localization (MBL) are prime examples of ergodicity breaking, yet their physical origin is quite different: the former phase arises due to rugged classical energy landscape, while the latter is a quantum-interference effect. Here we study quantum dynamics of an isolated 1d spin-glass under application of a transverse field. At high energy densities, the system is ergodic, relaxing via resonance avalanche mechanism, that is also responsible for the destruction of MBL in non-glassy systems with power-law interactions. At low energy densities, the interaction-induced fields obtain a power-law soft gap, making the resonance avalanche mechanism inefficient. This leads to the persistence of the spin-glass order, as demonstrated by resonance analysis and by numerical studies. A small fraction of resonant spins forms a thermalizing system with long-range entanglement, making this regime distinct from the conventional MBL. The model considered can be realized in systems of trapped ions, opening the door to investigating slow quantum dynamics induced by glassiness.
Amorphous solids such as glass are ubiquitous in our daily life and have found broad applications ranging from window glass and solar cells to telecommunications and transformer cores. However, due to the lack of long-range order, the three-dimensional (3D) atomic structure of amorphous solids have thus far defied any direct experimental determination without model fitting. Here, using a multi-component metallic glass as a proof-of-principle, we advance atomic electron tomography to determine the 3D atomic positions in an amorphous solid for the first time. We quantitatively characterize the short-range order (SRO) and medium-range order (MRO) of the 3D atomic arrangement. We find that although the 3D atomic packing of the SRO is geometrically disordered, some SRO connect with each other to form crystal-like networks and give rise to MRO. We identify four crystal-like MRO networks - face-centred cubic, hexagonal close-packed, body-centered cubic and simple cubic - coexisting in the sample, which show translational but no orientational order. These observations confirm that the 3D atomic structure in some parts of the sample is consistent with the efficient cluster packing model. Looking forward, we anticipate this experiment will open the door to determining the 3D atomic coordinates of various amorphous solids, whose impact on non-crystalline solids may be comparable to the first 3D crystal structure solved by x-ray crystallography over a century ago.
The ferromagnetic phase of an Ising model in d=3, with any amount of quenched antiferromagnetic bond randomness, is shown to undergo a transition to a spin-glass phase under sufficient quenched bond dilution. This general result, demonstrated here with the numerically exact renormalization-group solution of a d=3 hierarchical lattice, is expected to hold true generally, for the cubic lattice and for quenched site dilution. Conversely, in the ferromagnetic-spinglass-antiferromagnetic phase diagram, the spin-glass phase expands under quenched dilution at the expense of the ferromagnetic and antiferromagnetic phases. In the ferro-spinglass phase transition induced by quenched dilution reentrance is seen, as previously found for the ferro-spinglass transition induced by increasing the antiferromagnetic bond concentration.
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