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Register a new userThe Sub-millimeter Rotational Spectrum of Ethylene Glycol up to 890 GHz and Application to ALMA Band 10 Spectral Line Data of NGC 6334I
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The rotational spectrum of the most stable conformer of ethylene glycol (HO(CH$_2$)$_2$OH) has been recorded between 360-890 GHz using a frequency-modulation sub-millimeter spectrometer. The refinement and extension of the spectroscopic parameters over previous efforts provides predicted catalog frequencies for ethylene glycol with sufficient accuracy for comparison to high-frequency astronomical data. The improvement in the cataloged line positions, and the need for improved accuracy enabled by high-frequency laboratory work, is demonstrated by an analysis of ethylene glycol emission at 890 GHz in the high-mass star-forming region NGC 6334I in ALMA Band 10 observations. The need for accurate rotational spectra at sub-millimeter wavelengths/THz frequencies is discussed.
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We report the first detection and high angular resolution (1.8 $times$ 1.1) imaging of acetic acid (CH$_3$COOH) and gGg$^{prime}$--ethylene glycol (gGg$^{prime}$(CH$_2$OH)$_2$) towards the Orion Kleinmann--Low nebula. The observations were carried out at $sim$1.3mm with ALMA during the Cycle~2. A notable result is that the spatial distribution of the acetic acid and ethylene glycol emission differs from that of the other O-bearing molecules within Orion-KL. Indeed, while the typical emission of O-bearing species harbors a morphology associated with a V-shape linking the Hot Core region to the Compact Ridge (with an extension towards the BN object), that of acetic acid and ethylene glycol mainly peaks at about 2 southwest from the hot core region (near sources I and n). We find that the measured CH$_3$COOH:aGg$^{prime}$(CH$_2$OH)$_2$ and CH$_3$COOH:gGg$^{prime}$(CH$_2$OH)$_2$ ratios differ from the ones measured towards the low-mass protostar IRAS 16293--2422 by more than one order of magnitude. Our best hypothesis to explain these findings is that CH$_3$COOH, aGg$^{prime}$(CH$_2$OH)$_2$ and gGg$^{prime}$(CH$_2$OH)$_2$ are formed on the icy-surface of grains and then released into the gas-phase, via co-desorption with water, due to a bullet of matter ejected during the explosive event that occurred in the heart of the Nebula about 500-700 years ago.
Context. A possible correlation between CO luminosity (L_CO ) and its line width (FWHM) has been suggested and denied in the literature. Such claims were often based on a small, or heterogeneous sample of galaxies, and thus inconclusive. Aims. We aim to prove or dis-prove the L_CO -FWHM correlation. Methods. We compile a large sample of submm galaxies at z>2 from the literature, and investigate the L_CO-FWHM relation. Results. After carefully evaluating the selection effects and uncertainties such as inclination and magnification via gravitational lensing, we show that there exist a weak but significant correlation between L_CO and FWHM. We also discuss a feasibility to measure the cosmological distance using the correlation.
The Sloan Digital Sky Survey (SDSS) was revolutionary because of the extraordinary breadth and ambition of its optical imaging and spectroscopy. We argue that a sub-millimeter SDSS - a sensitive large-area imaging+spectroscopic survey in the sub-mm window - will revolutionize our understanding of galaxy evolution in the early Universe. By detecting the thermal dust continuum emission and atomic and molecular line emission of galaxies out to z~10 it will be possible to measure the redshifts, star formation rates, dust and gas content of hundreds of thousands of high-z galaxies down to ~L*. Many of these galaxies will have counterparts visible in the deep optical imaging of the Large Synoptic Survey Telescope. This 3D map of galaxy evolution will span the peak epoch of galaxy formation all the way back to cosmic dawn, measuring the co-evolution of the star formation rate density and molecular gas content of galaxies, tracking the production of metals and charting the growth of large-scale structure.
ALMA will revolutionize our understanding of star formation within our galaxy, but before we can use ALMA we need to know where to look. The Millimeter Astronomy Legacy Team 90 GHz (MALT90) Survey is a large international project to map the molecular line emission of over 2,000 dense clumps in the Galactic plane. MALT90 serves as a pathfinder for ALMA, providing a large public database of dense molecular clumps associated with high-mass star formation. In this proceedings, we describe the survey parameters and share early science highlights from the survey, including (1) a comparison between galactic and extragalactic star formation relations, (2) chemical trends in MALT90 clumps, (3) the distribution of high-mass star formation in the Milky Way, and (4) a discussion of the Brick, the target of successful ALMA Cycle 0 and Cycle 1 proposals.
Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this correlation because it was not easily detected in the interstellar medium although it proved to be rather abundant with respect to other O-bearing species in comet Hale-Bopp. Ethylene glycol thus appears, together with the related molecules glycolaldehyde CH$_{2}$OHCHO and ethanol CH$_{3}$CH$_{2}$OH, as a key species in the comparison of interstellar and cometary ices as well as in any discussion on the formation of cometary matter. We focus here on the analysis of ethylene glycol in the nearest and best studied hot core-like region, Orion-KL. We use ALMA interferometric data because high spatial resolution observations allow us to reduce the line confusion problem with respect to single-dish observations since different molecules are expected to exhibit different spatial distributions. Furthermore, a large spectral bandwidth is needed because many individual transitions are required to securely detect large organic molecules. Confusion and continuum subtraction are major issues and have been handled with care. We have detected the aGg conformer of ethylene glycol in Orion-KL. The emission is compact and peaks towards the Hot Core close to the main continuum peak, about 2 to the south-west; this distribution is notably different from other O-bearing species. Assuming optically thin lines and local thermodynamic equilibrium, we derive a rotational temperature of 145 K and a column density of 4.6 10$^{15}$ cm$^{-2}$. The limit on the column density of the gGg conformer is five times lower.
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