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Two-phase developing laminar mixing layer at supercritical pressures

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 Added by Branson Davis
 Publication date 2019
  fields Physics
and research's language is English




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Numerical analysis of a shear layer between a cool liquid n-decane hydrocarbon and a hot oxygen gas at supercritical pressures shows that a well-defined phase equilibrium can be established. Variable properties are considered with the product of density and viscosity in the gas phase showing a nearly constant result within the laminar flow region with no instabilities. Sufficiently thick diffusion layers form around the liquid-gas interface to support the case of continuum theory and phase equilibrium. While molecules are exchanged for both species at all pressures, net mass flux across the interface shifts as pressure is increased. Net vaporization occurs for low pressures while net condensation occurs at higher pressures. For a mixture of n-decane and oxygen, the transition occurs around 50 bar. The equilibrium values at the interface quickly reach their downstream asymptotes. For all cases, profiles of diffusing-advecting quantities collapse to a similar solution (i.e., function of one independent variable). Validity of the boundary layer approximation and similarity are shown in both phases for Reynolds numbers greater than 239 at 150 bar. Results for other pressures are also taken at high Reynolds numbers. Thereby, the validity of the boundary layer approximation and similarity are expected. However, at very high pressures, the similar one-dimensional profiles vary for different problem constraints.

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Previous works for a liquid suddenly contacting a gas at a supercritical pressure show the coexistence of both phases and the generation of diffusion layers on both sides of the liquid-gas interface due to thermodynamic phase equilibrium. A related numerical study of a laminar mixing layer between the liquid and gas streams in the near field of the splitter plate suggests that mass, momentum and thermal diffusion layers evolve in a self-similar manner at very high pressures. In this paper, the high-pressure, two-phase, laminar mixing-layer equations are recast in terms of a similarity variable. A liquid hydrocarbon and gaseous oxygen are considered. Freestream conditions and proper matching conditions at the liquid-gas interface are applied. To solve the system of equations, a real-fluid thermodynamic model based on the Soave-Redlich-Kwong equation of state is selected. A comparison with results obtained by directly solving the laminar mixing-layer equations shows the validity of the similarity approach applied to non-ideal two-phase flows. Even when the gas is hotter than the liquid, condensation can occur at high pressures while heat conducts into the liquid. Finally, a generalized correlation is proposed to represent the evolution of the mixing layer thickness for different problem setups.
Three-dimensional laminar flow structures with mixing, chemical reaction, normal strain, and shear strain qualitatively representative of turbulent combustion at the small scales are analyzed. A mixing layer is subjected to counterflow in the transverse y- and z-directions. Both non-reactive and reactive flows are examined. Reduction of the three-dimensional boundary-layer equations to a one-dimensional similar form is obtained allowing for heat and mass diffusion with variations in density and properties. In steady configurations, a set of ODEs governs the three velocity components as well as the scalar-field variables. A flamelet model for individual diffusion flames with combined shear and normal strain is developed. Another model with solution in similar form is obtained for a configuration with a dominant diffusion flame and a weaker fuel-rich premixed flame. Results for the velocity and scalar fields are found for ranges of Damkohler number Da, normal strain rate due to the counterflow, streamwise-velocity ratio across the mixing layer, Prandtl number, and Mach number. For the flamelet model, a conserved scalar is cast as the independent variable to give an alternative description of the results. The imposed normal strain decreases mixing-layer thickness and increases scalar gradients and transport rates. There is indication of diffusion control for partially premixed flames in the multi-branched flame situation. The enhancement of the mixing and combustion rates by imposed normal strain on a shear layer can be very substantial. Also, the imposition of shear strain and thereby vorticity on the counterflow can be substantial indicating the need for flamelet models with both shear strain and normal strain.
A two-phase, low-Mach-number flow solver is proposed for variable-density liquid and gas with phase change. The interface is captured using a split Volume-of-Fluid method, which solves the advection of the reference phase, generalized for the case where the liquid velocity is not divergence-free and both phases exchange mass. A sharp interface is identified by using PLIC. Mass conservation is achieved in the limit of incompressible liquid, but not with the liquid compressibility and mass exchange. This is a relevant modeling choice for two-phase mixtures at near-critical and supercritical pressure conditions for the liquid but away from the mixture critical temperature. Under this thermodynamic environment, the dissolution of lighter gas species into the liquid phase is enhanced and vaporization or condensation can occur simultaneously at different interface locations. The numerical challenge of solving two-phase, supercritical-pressure flows is greater than simpler two-phase solvers because: a) local phase equilibrium is imposed at each interface cell to determine temperature, composition, or surface tension coefficient; b) a real-fluid thermodynamic model is used to obtain fluid properties; and c) necessary phase-wise values for certain variables are obtained via extrapolation techniques. To alleviate the increased numerical cost, the pressure Poisson equation (PPE) used to solve the low-Mach-number flow is split into a constant-coefficient implicit part and a variable-coefficient explicit part. Thus, a Fast Fourier Transform method can be used for the PPE. Various verification tests are performed to show the accuracy and viability of the present approach. The growth of surface instabilities in a binary system composed of liquid n-decane and gaseous oxygen at supercritical pressures for n-decane is analyzed. Other features of supercritical liquid injection are also shown.
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This fluid dynamics video submitted to the Gallery of Fluid motion shows a turbulent boundary layer developing under a 5 metre-long flat plate towed through water. A stationary imaging system provides a unique view of the developing boundary layer as it would form over the hull of a ship or fuselage of an aircraft. The towed plate permits visualisation of the zero-pressure-gradient turbulent boundary layer as it develops from the trip to a high Reynolds number state ($Re_tau approx 3000$). An evolving large-scale coherent structure will appear almost stationary in this frame of reference. The visualisations provide an unique view of the evolution of fundamental processes in the boundary layer (such as interfacial bulging, entrainment, vortical motions, etc.). In the more traditional laboratory frame of reference, in which fluid passes over a stationary body, it is difficult to observe the full evolution and lifetime of turbulent coherent structures. An equivalent experiment in a wind/water-tunnel would require a camera and laser that moves with the flow, effectively `chasing eddies as they advect downstream.
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