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Register a new userDynamic and programmable cellular-scale granules enable tissue-like materials
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Tissue-like materials are required in many robotic systems to improve human-machine interactions. However, the mechanical properties of living tissues are difficult to replicate. Synthetic materials are not usually capable of simultaneously displaying the behaviors of the cellular ensemble and the extracellular matrix. A particular challenge is identification of a cell-like synthetic component which is tightly integrated with its matrix and also responsive to external stimuli at the population level. Here, we demonstrate that cellular-scale hydrated starch granules, an underexplored component in materials science, can turn conventional hydrogels into tissue-like materials when composites are formed. Using several synchrotron-based X-ray techniques, we reveal the mechanically-induced motion and training dynamics of the starch granules in the hydrogel matrix. These dynamic behaviors enable multiple tissue-like properties such as strain-stiffening, anisotropy, mechanical heterogeneity, programmability, mechanochemistry, impact absorption, and self-healability. The starch-hydrogel composites can be processed as robotic skins that maintain these tissue-like characteristics.
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Using X- ray photon correlation spectroscopy measurements on gold nanoparticles embedded in polymethylmethacrylate we provide evidence for existence of an intrinsic length scale for dynamic heterogeneity in polymer nanocomposites similar to that in other soft materials.We also show how the dynamics varies in a complex way with various parameters.
Granular packings of non-convex or elongated particles can form free-standing structures like walls or arches. For some particle shapes, such as staples, the rigidity arises from interlocking of pairs of particles, but the origins of rigidity for non-interlocking particles remains unclear. We report on experiments and numerical simulations of sheared columns of hexapods, particles consisting of three mutually orthogonal sphero-cylinders whose centers coincide. We vary the length-to-diameter aspect ratio, $alpha$, of the sphero-cylinders and subject the packings to quasistatic direct shear. For small $alpha$, we observe a finite yield stress. For large $alpha$, however, the column becomes rigid when sheared, supporting stresses that increase sharply with increasing strain. Analysis of X-ray micro-computed tomography (Micro-CT) data collected during the shear reveals that the stiffening is associated with a tilted, oblate cluster of hexapods near the nominal shear plane in which particle deformation and average contact number both increase. Simulation results show that the particles are collectively under tension along one direction even though they do not interlock pairwise. These tensions comes from contact forces carrying large torques, and they are perpendicular to the compressive stresses in the packing. They counteract the tendency to dilate, thus stabilize the particle cluster.
Topological aspects of the geometry of DNA and similar chiral molecules have received a lot of attention, while the topology of their electronic structure is less explored. Previous experiments have revealed that DNA can efficiently filter spin-polarized electrons between metal contacts, a process called chiral-induced spin-selectivity (CISS). However, the underlying correlation between chiral structure and electronic spin remains elusive. In this work, we reveal an orbital texture in the band structure, a topological characteristic induced by the chirality. We find that this orbital texture enables the chiral molecule to polarize the quantum orbital. This orbital polarization effect (OPE) induces spin polarization assisted by the spin-orbit interaction from a metal contact and leads to magnetorestistance and chiral separation. The orbital angular momentum of photoelectrons also plays an essential role in related photoemission experiments. Beyond CISS, we predict that OPE can induce spin-selective phenomena even in achiral but inversion-breaking materials.
Predicting when rupture occurs or cracks progress is a major challenge in numerous elds of industrial, societal and geophysical importance. It remains largely unsolved: Stress enhancement at cracks and defects, indeed, makes the macroscale dynamics extremely sensitive to the microscale material disorder. This results in giant statistical uctuations and non-trivial behaviors upon upscaling dicult to assess via the continuum approaches of engineering. These issues are examined here. We will see: How linear elastic fracture mechanics sidetracks the diculty by reducing the problem to that of the propagation of a single crack in an eective material free of defects, How slow cracks sometimes display jerky dynamics, with sudden violent events incompatible with the previous approach, and how some paradigms of statistical physics can explain it, How abnormally fast cracks sometimes emerge due to the formation of microcracks at very small scales.
Recent experimental results on the static or quasistatic response of granular materials have been interpreted to suggest the inapplicability of the traditional engineering approaches, which are based on elasto-plastic models (which are elliptic in nature). Propagating (hyperbolic) or diffusive (parabolic) models have been proposed to replace the `old models. Since several recent experiments were performed on small systems, one should not really be surprised that (continuum) elasticity, a macroscopic theory, is not directly applicable, and should be replaced by a grain-scale (``microscopic) description. Such a description concerns the interparticle forces, while a macroscopic description is given in terms of the stress field. These descriptions are related, but not equivalent, and the distinction is important in interpreting the experimental results. There are indications that at least some large scale properties of granular assemblies can be described by elasticity, although not necessarily its isotropic version. The purely repulsive interparticle forces (in non-cohesive materials) may lead to modifications of the contact network upon the application of external forces, which may strongly affect the anisotropy of the system. This effect is expected to be small (in non-isostatic systems) for small applied forces and for pre-stressed systems (in particular for disordered systems). Otherwise, it may be accounted for using a nonlinear, incrementally elastic model, with stress-history dependent elastic moduli. Although many features of the experiments may be reproduced using models of frictionless particles, results demonstrating the importance of accounting for friction are presented.
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