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Register a new userQuantum efficiency enhancement of bialkali photocathodes by an atomically thin layer on substrates
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We report quantum efficiency (QE) enhancements in accelerator technology relevant antimonide photocathodes (K2CsSb) by interfacing them with atomically thin two-dimensional (2D) crystal layers. The enhancement occurs in a reflection mode, when a 2D crystal is placed in between the photocathodes and optically reflective substrates. Specifically, the peak QE at 405 nm (3.1 eV) increases by a relative 10 percent, while the long wavelength response at 633 nm (2.0 eV) increases by a relative 36 percent on average and up to 80 percent at localized hot spot regions when photocathodes are deposited onto graphene coated stainless steel. There is a similar effect for photocathodes deposited on hexagonal boron nitride monolayer coatings using nickel substrates. The enhancement does not occur when reflective substrates are replaced with optically transparent sapphire. Optical transmission, X-ray diffraction (XRD) and X-ray fluorescence (XRF) revealed that thickness, crystal orientation, quality and elemental stoichiometry of photocathodes do not appreciably change due to 2D crystal coatings. These results suggest optical interactions are responsible for the QE enhancements when 2D crystal sublayers are present on reflective substrates, and provide a pathway toward a simple method of QE enhancement in semiconductor photocathodes by an atomically thin 2D crystal on substrates.
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Aspects of the preparation process and performance degradation are two major problems of photocathodes. The lack of a means for dynamic quantum efficiency measurements results in the inability to observe the inhomogeneity of the cathode surface by fine structural analysis and in real time.Here we present a simple and scalable technique for in situ real-time quantum efficiency diagnosis. An incoherent light source provides uniform illumination on the cathode surface, and solenoid magnets are used as lens for focusing and imaging the emitted electron beam on a downstream scintillator screen, which converts the quantum efficiency information into fluorescence intensity distribution. The microscopic discontinuity and the dynamic changes of the quantum efficiency of a gallium arsenide photocathode are observed at a resolution of a few microns. An unexpected uneven decrease of the quantum efficiency is also recorded. The work demonstrates a new observation method for photoemission materials research.
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