Naturalistic driving trajectories are crucial for the performance of autonomous driving algorithms. However, most of the data is collected in safe scenarios leading to the duplication of trajectories which are easy to be handled by currently developed algorithms. When considering safety, testing algorithms in near-miss scenarios that rarely show up in off-the-shelf datasets is a vital part of the evaluation. As a remedy, we propose a near-miss data synthesizing framework based on Variational Bayesian methods and term it as Conditional Multiple Trajectory Synthesizer (CMTS). We leverage a generative model conditioned on road maps to bridge safe and collision driving data by representing their distribution in the latent space. By sampling from the near-miss distribution, we can synthesize safety-critical data crucial for understanding traffic scenarios but not shown in neither the original dataset nor the collision dataset. Our experimental results demonstrate that the augmented dataset covers more kinds of driving scenarios, especially the near-miss ones, which help improve the trajectory prediction accuracy and the capability of dealing with risky driving scenarios.