Semidefinite and sum-of-squares (SOS) optimization are fundamental computational tools in many areas, including linear and nonlinear systems theory. However, the scale of problems that can be addressed reliably and efficiently is still limited. In this paper, we introduce a new notion of emph{block factor-width-two matrices} and build a new hierarchy of inner and outer approximations of the cone of positive semidefinite (PSD) matrices. This notion is a block extension of the standard factor-width-two matrices, and allows for an improved inner-approximation of the PSD cone. In the context of SOS optimization, this leads to a block extension of the emph{scaled diagonally dominant sum-of-squares (SDSOS)} polynomials. By varying a matrix partition, the notion of block factor-width-two matrices can balance a trade-off between the computation scalability and solution quality for solving semidefinite and SOS optimization. Numerical experiments on large-scale instances confirm our theoretical findings.
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