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Comparing compositional models of the terrestrial planets provides insights into physicochemical processes that produced planet-scale similarities and differences. The widely accepted compositional model for Mars assumes Mn and more refractory elements are in CI chondrite proportions in the planet, including Fe, Mg, and Si, which along with O make up $>$90% of the mass of Mars. However, recent improvements in our understandings on the composition of the solar photosphere and meteorites challenge the use of CI chondrite as an analog of Mars. Here we present an alternative model composition for Mars that avoids such an assumption and is based on data from Martian meteorites and spacecraft observations. Our modeling method was previously applied to predict the Earths composition. The model establishes the absolute abundances of refractory lithophile elements in the bulk silicate Mars (BSM) at 2.26 times higher than that in CI carbonaceous chondrites. Relative to this chondritic composition, Mars has a systematic depletion in moderately volatile lithophile elements as a function of their condensation temperatures. Given this finding, we constrain the abundances of siderophile and chalcophile elements in the bulk Mars and its core. The Martian volatility trend is consistent with $ leq $7 wt% S in its core, which is significantly lower than that assumed in most core models (i.e., $ > $10 wt% S). Furthermore, the occurrence of ringwoodite at the Martian core-mantle boundary might have contributed to the partitioning of O and H into the Martian core.
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We have used the XSHOOTER echelle spectrograph on the European Southern Obseratory (ESO) Very Large Telescope (VLT) to obtain UVB-VIS-NIR (ultraviolet-blue (UVB), visible (VIS) and near-infrared (NIR)) reflectance spectra of two members of the Eureka family of L5 Mars Trojans, in order to test a genetic relationship to Eureka. In addition to obtaining spectra, we also carried out VRI photometry of one of the VLT targets using the 2-m telescope at the Bulgarian National Astronomical Observatory - Rozhen and the two-channel focal reducer. We found that these asteroids belong to the olivine-dominated A, or Sa, taxonomic class. As Eureka itself is also an olivine-dominated asteroid, it is likely that all family asteroids share a common origin and composition. We discuss the significance of these results in terms of the origin of the martian Trojan population.
In the past, constraining the surface composition of near-Earth asteroids (NEAs) has been difficult due to the lack of high quality near-IR spectral data (0.7-2.5 microns) that contain mineralogically diagnostic absorption bands. Here we present visible (0.43-0.95 microns) and near-infrared (0.7-2.5 microns) spectra of nine NEAs and five Mars-crossing asteroids (MCs). The studied NEAs are: 4055 Magellan, 19764 (2000 NF5), 89830 (2002 CE), 138404 (2000 HA24), 143381 (2003 BC21), 159609 (2002 AQ3), 164121 (2003 YT1), 241662 (2000 KO44) and 2007 ML13. The studied MCs are: 1656 Suomi, 2577 Litva, 5407 (1992 AX), 22449 Ottijeff and 47035 (1998 WS). The observations were conducted with the NTT at La Silla, Chile, the 2.2 m telescope at Calar Alto, Spain, and the IRTF on Mauna Kea, Hawaii. The taxonomic classification (Bus system) of asteroids showed that all observed MC asteroids belong to the S-complex, including the S, Sr and Sl classes. Seven of the NEAs belong to the S-complex, including the S, Sa, Sk and Sl classes, and two NEAs were classified as V-types. The classification of the NEA 164121 (2003 YT1) as a V-type was made on the basis of its near-infrared spectrum since no visible spectrum is available for this asteroid. A mineralogical analysis was performed on six of the asteroids (those for which near-IR spectra were obtained or previously available). We found that three asteroids (241662 (2000 KO44), 19764 (2000 NF5), 138404 (2000 HA24)) have mafic silicate compositions consistent with ordinary chondrites, while three others (4055 Magellan, 164121 (2003 YT1), 5407 (1992 AX)) are pyroxene-dominated basaltic achondrite assemblages. In the case of 5407 (1992 AX) we found that its basaltic surface composition contrasts its taxonomic classification as a S-type.
The Mars Express (MEX) mission has been successfully operated around Mars since 2004. Among many results, MEX has provided some of the most accurate astrometric data of the two Mars moons, Phobos and Deimos. In this work we present new ephemerides of Mars moons benefitting from all previously published astrometric data to the most recent MEX SRC data. All in all, observations from 1877 until 2018 and including spacecraft measurements from Mariner 9 to MEX were included. Assuming a homogeneous interior, we fitted Phobos forced libration amplitude simultaneously with the Martian tidal k2/Q ratio and the initial state of the moons. Our solution of the physical libration 1.09 +/- 0.01 degrees deviates notably from the homogeneous solution. But considering the very low error bar, this may essentially suggest the necessity to consider higher order harmonics, with an improved rotation model, in the future. While most data could be successfully fitted, we found a disagreement between the Mars Reconnaissance Orbiter and the Mars Express astrometric data at the kilometer level probably associated with a biased phase correction. The present solution precision is expected at the level of a few hundreds of meters for Phobos and several hundreds of meters for Deimos for the coming years. The real accuracy of our new ephemerides will have to be confirmed by confrontation with independent observational means.
We have obtained the first continuous disk averaged spectrum of Mars from 450 to 1550 Ghz using the Herschel-SPIRE Fourier Transform Spectrometer. The spectrum was obtained at a constant resolution of 1.4 GHz across the whole band. The flux from the planet is such that the instrument was operated in bright source mode to prevent saturation of the detectors. This was the first successful use of this mode and in this work we describe the method used for observing Mars together with a detailed discussion of the data reduction techniques required to calibrate the spectrum. We discuss the calibration accuracy obtained and describe the first comparison with surface and atmospheric models. In addition to a direct photometric measurement of the planet the spectrum contains the characteristic transitions of 12CO from J 5-4 to J 13-12 as well as numerous H2O transitions. Together these allow the comparison to global atmospheric models allowing the mean mixing ratios of water and 12CO to be investigated. We find that it is possible to match the observed depth of the absorption features in the spectrum with a fixed water mixing ratio of 1 x 10-4 and a 12CO mixing ratio of 9 x 10-4
The history of rivers on Mars is an important constraint on Martian climate evolution. The timing of relatively young, alluvial fan-forming rivers is especially important, as Mars Amazonian atmosphere is thought to have been too thin to consistently support surface liquid water. Previous regional studies suggested that alluvial fans formed primarily between the Early Hesperian and the Early Amazonian. In this study, we describe how a combination of a global impact crater database, a global geologic map, a global alluvial fan database, and statistical models can be used to estimate the timing of alluvial fan formation across Mars. Using our global approach and improved statistical modeling, we find that alluvial fan formation likely persisted into the last ~2.5 Gyr, well into the Amazonian period. However, the data we analyzed was insufficient to place constraints on the duration of alluvial fan formation. Going forward, more crater data will enable tighter constraints on the parameters estimated in our models and thus further inform our understanding of Mars climate evolution.
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