Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userNear-equilibrium isotope fractionation during planetesimal evaporation
102
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Silicon and Mg in differentiated rocky bodies exhibit heavy isotope enrichments that have been attributed to evaporation of partially or entirely molten planetesimals. We evaluate the mechanisms of planetesimal evaporation in the early solar system and the conditions that controlled attendant isotope fractionations. Energy balance at the surface of a body accreted within ~1 Myr of CAI formation and heated from within by 26Al decay results in internal temperatures exceeding the silicate solidus, producing a transient magma ocean with a thin surface boundary layer of order < 1 meter that would be subject to foundering. Bodies that are massive enough to form magma oceans by radioisotope decay (ge 0.1%) can retain hot rock vapor even in the absence of ambient nebular gas. We find that a steady-state rock vapor forms within minutes to hours and results from a balance between rates of magma evaporation and atmospheric escape. Vapor pressure buildup adjacent to the surfaces of the evaporating magmas would have inevitably led to an approach to equilibrium isotope partitioning between the vapor phase and the silicate melt. Numerical simulations of this near-equilibrium evaporation process for a body with a radius of ~ 700 km yield a steady-state far-field vapor pressure corresponding to 95% saturation. Approaches to equilibrium isotope fractionation between vapor and melt should have been the norm during planet formation due to the formation of steady-state rock vapor atmospheres and/or the presence of protostellar gas. We model the Si and Mg isotopic composition of bulk Earth and show that the best fit is for a carbonaceous chondrite-like source material with about 12% loss of Mg and 15% loss of Si resulting from near-equilibrium evaporation into the solar protostellar disk of hydrogen gas on timescales of 10,000 to 100,000 years.
rate research
Read More
Finding and characterizing extrasolar Earth analogs will rely on interpretation of the planetary systems environmental context. The total budget and fractionation between C-H-O species sensitively affect the climatic and geodynamic state of terrestrial worlds, but their main delivery channels are poorly constrained. We connect numerical models of volatile chemistry and pebble coagulation in the circumstellar disk with the internal compositional evolution of planetesimals during the primary accretion phase. Our simulations demonstrate that disk chemistry and degassing from planetesimals operate on comparable timescales and can fractionate the relative abundances of major water and carbon carriers by orders of magnitude. As a result, individual planetary systems with significant planetesimal processing display increased correlation in the volatile budget of planetary building blocks relative to no internal heating. Planetesimal processing in a subset of systems increases the variance of volatile contents across planetary systems. Our simulations thus suggest that exoplanetary atmospheric compositions may provide constraints on $when$ a specific planet formed.
Aims: The two stable isotopes of nitrogen, 14N and 15N, exhibit a range of abundance ratios both inside and outside the solar system. The elemental ratio in the solar neighborhood is 440. Recent ALMA observations showed HCN/HC15N ratios from 83 to 156 in six T Tauri and Herbig disks and a CN/C15 N ratio of 323 +/- 30 in one T Tauri star. We aim to determine the dominant mechanism responsible for these enhancements of 15N: low-temperature exchange reactions or isotope-selective photodissociation of N2. Methods: Using the thermochemical code DALI, we model the nitrogen isotope chemistry in circumstellar disks with a 2D axisymmetric geometry. Our chemical network is the first to include both fractionation mechanisms for nitrogen. The model produces abundance profiles and isotope ratios for several key N-bearing species. We study how these isotope ratios depend on various disk parameters. Results: The formation of CN and HCN is closely coupled to the vibrational excitation of H2 in the UV-irradiated surface layers of the disk. Isotope fractionation is completely dominated by isotope-selective photodissociation of N2. The column density ratio of HCN over HC15N in the disks inner 100 au does not depend strongly on the disk mass, the flaring angle or the stellar spectrum, but it is sensitive to the grain size distribution. For larger grains, self-shielding of N2 becomes more important relative to dust extinction, leading to stronger isotope fractionation. Between disk radii of ~50 and 200 au, the models predict HCN/HC15N and CN/C15N abundance ratios consistent with observations of disks and comets. The HCN/HC15N and CN/C15N column density ratios in the models are a factor of 2-3 higher than those inferred from the ALMA observations.
Chondrules are the dominant bulk silicate constituent of chondritic meteorites and originate from highly energetic, local processes during the first million years after the birth of the Sun. So far, an astrophysically consistent chondrule formation scenario, explaining major chemical, isotopic and textural features, remains elusive. Here, we examine the prospect of forming chondrules from planetesimal collisions. We show that intensely melted bodies with interior magma oceans became rapidly chemically equilibrated and physically differentiated. Therefore, collisional interactions among such bodies would have resulted in chondrule-like but basaltic spherules, which are not observed in the meteoritic record. This inconsistency with the expected dynamical interactions hints at an incomplete understanding of the planetary growth regime during the protoplanetary disk phase. To resolve this conundrum, we examine how the observed chemical and isotopic features of chondrules constrain the dynamical environment of accreting chondrite parent bodies by interpreting the meteoritic record as an impact-generated proxy of planetesimals that underwent repeated collision and reaccretion cycles. Using a coupled evolution-collision model we demonstrate that the vast majority of collisional debris feeding the asteroid main belt must be derived from planetesimals which were partially molten at maximum. Therefore, the precursors of chondrite parent bodies either formed primarily small, from sub-canonical aluminum-26 reservoirs, or collisional destruction mechanisms were efficient enough to shatter planetesimals before they reached the magma ocean phase. Finally, we outline the window in parameter space for which chondrule formation from planetesimal collisions can be reconciled with the meteoritic record and how our results can be used to further constrain early solar system dynamics.
We investigate the gas-phase and grain-surface chemistry in the inner 30 AU of a typical protoplanetary disk using a new model which calculates the gas temperature by solving the gas heating and cooling balance and which has an improved treatment of the UV radiation field. We discuss inner-disk chemistry in general, obtaining excellent agreement with recent observations which have probed the material in the inner regions of protoplanetary disks. We also apply our model to study the isotopic fractionation of carbon. Results show that the fractionation ratio, 12C/13C, of the system varies with radius and height in the disk. Different behaviour is seen in the fractionation of different species. We compare our results with 12C/13C ratios in the Solar System comets, and find a stark contrast, indicative of reprocessing.
The formation of organic compounds is generally assumed to result from abiotic processes in the Solar System, with the exception of biogenic organics on Earth. Nitrogen-bearing organics are of particular interest, notably for prebiotic perspectives but also for overall comprehension of organic formation in the young solar system and in planetary atmospheres. We have investigated abiotic synthesis of organics upon plasma discharge, with special attention to N isotope fractionation. Organic aerosols were synthesized from N2-CH4 and N2-CO gaseous mixtures using low-pressure plasma discharge experiments, aimed at simulating chemistry occurring in Titan s atmosphere and in the protosolar nebula, respectively. Nitrogen is efficiently incorporated into the synthesized solids, independently of the oxidation degree, of the N2 content of the starting gas mixture, and of the nitrogen speciation in the aerosols. The aerosols are depleted in 15N by 15-25 permil relative to the initial N2 gas, whatever the experimental setup is. Such an isotopic fractionation is attributed to mass-dependent kinetic effect(s). Nitrogen isotope fractionation upon electric discharge cannot account for the large N isotope variations observed among solar system objects and reservoirs. Extreme N isotope signatures in the solar system are more likely the result of self-shielding during N2 photodissociation, exotic effect during photodissociation of N2 and/or low temperature ion-molecule isotope exchange. Kinetic N isotope fractionation may play a significant role in the Titan s atmosphere. We also suggest that the low delta15N values of Archaean organic matter are partly the result of abiotic synthesis of organics that occurred at that time.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
