We construct proper good moduli spaces parametrizing K-polystable $mathbb{Q}$-Gorenstein smoothable log Fano pairs $(X, cD)$, where $X$ is a Fano variety and $D$ is a rational multiple of the anti-canonical divisor. We then establish a wall-crossing framework of these K-moduli spaces as $c$ varies. The main application in this paper is the case of plane curves of degree $d geq 4$ as boundary divisors of $mathbb{P}^2$. In this case, we show that when the coefficient $c$ is small, the K-moduli space of these pairs is isomorphic to the GIT moduli space. We then show that the first wall crossing of these K-moduli spaces are weighted blow-ups of Kirwan type. We also describe all wall crossings for degree 4,5,6, and relate the final K-moduli spaces to Hackings compactification and the moduli of K3 surfaces.