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Planet atmosphere and hydrosphere compositions are fundamentally set by accretion of volatiles, and therefore by the division of volatiles between gas and solids in planet-forming disks. For hyper-volatiles such as CO, this division is regulated by a combination of binding energies, and by the ability of other ice components to entrap. Water ice is known for its ability to trap CO and other volatile species. In this study we explore whether another common interstellar and cometary ice component, CO2, is able to trap CO as well. We measure entrapment of CO molecules in CO2 ice through temperature programmed desorption (TPD) experiments on CO2:CO ice mixtures. We find that CO2 ice traps CO with a typical efficiency of 40-60% of the initially deposited CO molecules for a range of ice thicknesses between 7 and 50ML, and ice mixture ratios between 1:1 and 9:1. The entrapment efficiency increases with ice thickness and CO dilution. We also run analogous H2O:CO experiments and find that under comparable experimental conditions CO2 ice entraps CO more efficiently than H2O ice up to the onset of CO2 desorption at ~70K. We speculate that this may be due to different ice restructuring dynamics in H2O and CO2 ices around the CO desorption temperature. Importantly, the ability of CO2 to entrap CO may change the expected division between gas and solids for CO and other hyper-volatiles exterior to the CO2 snowline during planet formation.
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Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO2 dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone.
We investigate the feasibility and demonstrate the merits of using Mars Orbiter Laser Altimeter (MOLA) profiles to retrieve seasonal height variations of CO2 snow/ice cap in Mars polar areas by applying a co-registration strategy. We present a prototype analysis on the research region of [85.75{deg}S, 86.25{deg}S, 300{deg}E, 330{deg}E] that is located on the residual south polar cap. Our method comprises the recomputation of MOLA footprint coordinates with an updated Mars Global Surveyor (MGS) ephemeris and a revised Mars rotation model. The reprocessed MOLA dataset at the South Pole of Mars (poleward of 78{deg}S) is then self-registered to form a coherent reference digital terrain model (DTM). We co-register segments of reprocessed MOLA profiles to the self-registered MOLA reference DTM to obtain the temporal height differences at either footprints or cross-overs. Subsequently, a two-step Regional Pseudo Cross-over Adjustment (RPCA) procedure is proposed and applied to post-correct the aforementioned temporal height differences for a temporal systematic bias and other residual errors. These pseudo cross-overs are formed by profile pairs that do not necessarily intersect, but are connected through the underlaying DTM. Finally, CO2 snow/ice temporal height variation is obtained by median-filtering those post-corrected temporal height differences. The precision of the derived height change time series is ~4.9 cm. The peak-to-peak height variation is estimated to be ~2 m. In addition, a pronounced pit (transient height accumulation) of ~0.5 m in magnitude centered at Ls=210{deg} in southern spring is observed. The proposed method opens the possibility to map the seasonal CO2 snow/ice height variations at the entire North and South polar regions of Mars.
The 163 comets observed during the WISE/NEOWISE prime mission represent the largest infrared survey to date of comets, providing constraints on dust, nucleus sizes, and CO+CO2 production. We present detailed analyses of the WISE/NEOWISE comet discoveries, and discuss observations of the active comets showing 4.6 $mu$m band excess. We find a possible relation between dust and CO+CO2 production, as well as possible differences in the sizes of long and short period comet nuclei.
Owing to their wavelengths dependent absorption and scattering properties, clouds have a strong impact on the climate of planetary atmospheres. Especially, the potential greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. We study the radiative effects of CO2 ice particles obtained by different numerical treatments to solve the radiative transfer equation. The comparison between the results of a high-order discrete ordinate method and simpler two-stream approaches reveals large deviations in terms of a potential scattering efficiency of the greenhouse effect. The two-stream methods overestimate the transmitted and reflected radiation, thereby yielding a higher scattering greenhouse effect. For the particular case of a cool M-type dwarf the CO2 ice particles show no strong effective scattering greenhouse effect by using the high-order discrete ordinate method, whereas a positive net greenhouse effect was found in case of the two-stream radiative transfer schemes. As a result, previous studies on the effects of CO2 ice clouds using two-stream approximations overrated the atmospheric warming caused by the scattering greenhouse effect. Consequently, the scattering greenhouse effect of CO2 ice particles seems to be less effective than previously estimated. In general, higher order radiative transfer methods are necessary to describe the effects of CO2 ice clouds accurately as indicated by our numerical radiative transfer studies.
Clouds have a strong impact on the climate of planetary atmospheres. The potential scattering greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. Here, the impact of CO2 ice clouds on the surface temperatures of terrestrial planets with CO2 dominated atmospheres, orbiting different types of stars is studied. Additionally, their corresponding effect on the position of the outer habitable zone boundary is evaluated. For this study, a radiative-convective atmospheric model is used the calculate the surface temperatures influenced by CO2 ice particles. The clouds are included using a parametrised cloud model. The atmospheric model includes a general discrete ordinate radiative transfer that can describe the anisotropic scattering by the cloud particles accurately. A net scattering greenhouse effect caused by CO2 clouds is only obtained in a rather limited parameter range which also strongly depends on the stellar effective temperature. For cool M-stars, CO2 clouds only provide about 6 K of additional greenhouse heating in the best case scenario. On the other hand, the surface temperature for a planet around an F-type star can be increased by 30 K if carbon dioxide clouds are present. Accordingly, the extension of the habitable zone due to clouds is quite small for late-type stars. Higher stellar effective temperatures, on the other hand, can lead to outer HZ boundaries about 0.5 au farther out than the corresponding clear-sky values.
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