Impacts of spin-polarization of an ultrarelativistic electron beam head-on colliding with a strong laser pulse on emitted photon spectra and electron dynamics have been investigated in the quantum radiation regime. We simulate photon emissions quantum mechanically and electron dynamics semiclassically via taking spin-resolved radiation probabilities in the local constant field approximation. A small ellipticity of the laser field brings about an asymmetry in angle-resolved photon spectrum, which sensitively relies on the polarization of the electron beam. The asymmetry is particularly significant in high-energy photon spectra, and is employed for the polarization detection of a high-energy electron beam with extraordinary precision, e.g., better than 0.3% for a few-GeV electron beam at a density of the scale of $10^{16}$ cm$^{-3}$ with currently available strong laser fields. This method demonstrates for the first time a way of single-shot determination of polarization for ultrarelativistic electron beams via nonlinear Compton scattering. A similar method based on the asymmetry in the electron momentum distribution after the interaction due to spin-dependent radiation reaction is proposed as well.
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