We present IRAM 30m observations of molecular lines of CO and its isotopologues from the massive spiral galaxy NGC 5908 selected from the CGM-MASS sample. $^{12}$CO $J=1-0$, $^{12}$CO $J=2-1$, and $^{13}$CO $J=1-0$ lines have been detected in most of the positions along the galactic disk. The total molecular gas mass of NGC 5908 is $sim7times10^9rm~M_odot$ and the total cool gas mass adding atomic hydrogen is $sim1.3times10^{10}rm~M_odot$, comparable to the upper limit of the mass of the X-ray emitting hot gas in the halo. Modeling the rotation curves constructed with all three CO lines indicates that NGC 5908 has a dark matter halo mass of $M_{rm vir}sim10^{13}rm~M_{rm odot}$, putting it among the most massive isolated spiral galaxies. The $^{12}$CO/$^{13}$CO $J=1-0$, $^{12}$CO $J=2-1$/$J=1-0$ line ratios and the estimated molecular gas temperature all indicate normal but non-negligible star formation in this fairly gas-rich massive isolated spiral galaxy, consistent with the measured star formation intensity and surface densities. The galaxy is probably at an early evolutionary stage after a fast growth stage with mergers and/or starbursts, with plenty of leftover cool gas, relatively high SFR, low hot CGM cooling rate, and low X-ray emissivity.
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