We present a critical review of the determination of fundamental parameters of white dwarfs discovered by the Gaia mission. We first reinterpret color-magnitude and color-color diagrams using photometric and spectroscopic information contained in the Montreal White Dwarf Database (MWDD), combined with synthetic magnitudes calculated from a self-consistent set of model atmospheres with various atmospheric compositions. The same models are then applied to measure the fundamental parameters of white dwarfs using the so-called photometric technique, which relies on the exquisite Gaia trigonometric parallax measurements, and photometric data from Pan-STARRS, SDSS, and Gaia. In particular, we discuss at length the systematic effects induced by these various photometric systems. We then study in great detail the mass distribution as a function of effective temperature for the white dwarfs spectroscopically identified in the MWDD, as well as for the white dwarf candidates discovered by Gaia. We pay particular attention to the assumed atmospheric chemical composition of cool, non-DA stars. We also briefly revisit the validity of the mass-radius relation for white dwarfs, and the recent discovery of the signature of crystallization in the Gaia color-magnitude diagram for DA white dwarfs. We finally present evidence that the core composition of most of these white dwarfs is, in bulk, a mixture of carbon and oxygen, an expected result from stellar evolution theory, but never empirically well established before.
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